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Найденный: 23 Экземпляр 0.000 sn
Год публикации [1]
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Synthesis, characterization, and application of silver nanoparticle-thiophenol nanocomposite film on the glassy carbon surface

Ali Osman SOLAK

In this study, 4-thiophenol modified glassy carbon electrode was prepared by the reduction of 4-diazothiophenol tetrafluoroborate salt. Silver nanoparticles were attached to the thiophenol modified surface to prepare a thiophenol-silver nanoparticle composite film. 4-Aminothiopenol molecules were deposited by self-assembling technique to form multi-layered nanofilms of TP/SNP/PhNH2 on glassy carbon substrate. These surfaces were characterized by cyclic voltammetry, electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy, reflectance-absorption infrared spectroscopy, and ellips ...Более

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Biofuel Cell Based on Anode and Cathode Modified by Glucose Oxidase

Ali Osman SOLAK

A single compartment biofuel cell (BFC) based on an anode and a cathode powered by the same fuel glucose is reported. Glucose oxidase (GOx) from Aspergillus niger was applied as a glucose consuming biocatalyst for both anode and cathode of the BFC. The 5-amino-1,10-phenanthroline modified graphite rod electrode (GRE) with cross-linked GOx was used as the bioanode, and the GRE with co-immobilised horseradish peroxidase and GOx was exploited as the biocathode of the BFC. The open-circuit voltage of the designed BFC exceeded 450 mV and a maximal power density of 3.5 µW/cm2 was registered at a cel ...Более

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Detection of Escherichia coli O157:H7 using immunomagnetic separation and mPCR in Turkish foods of animal origin

Zafer GÖNÜLALAN

The present study was conducted to investigate the presence of Escherichia coli O157:H7 in food samples of animal origin and to detect its virulence genes by immunomagnetic separation technique and multiplex PCR (mPCR). A total of 500 samples (consisting of diced meat, minced meat, burger, raw cow's milk and raw cow's milk cheese) were analysed. Escherichia coli O157:H7 was detected in 5 (1%) of 500 analysed samples including two diced meat, one minced meat and two raw-milk cheese. None of the burger samples tested contained E. coli O157:H7. Three isolates obtained from minced and diced meat w ...Более

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Two new records of the Coniopteryx (Neuroptera: Coniopterygidae) species for the Turkish fauna

Savaş CANBULAT

Two species of the family Coniopterygidae, Coniopteryx (Xeroconiopteryx) loipetsederi H. Aspöck, 1963 and C. (Coniopteryx) borealis Tjeder, 1931, are here recorded for the first time in the Turkish fauna. Morphological and ecological notes as well as the distribution map with new recording sites are also provided. For C. loipetsederi, this is the most eastern record, and the eastern limits of the range of C. borealis have also been extended. - Keywords: Neuroptera, Coniopterygidae, Coniopteryx loipetsederi, Coniopteryx borealis, new records, Turkey

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Formation of the plexus sacralis in pheasants (Phasianus colchicus mongolicus) and macroanatomic investigation of the nerves originating from the plexus sacralis

Fatih Ramazan İSTANBULLUGİL | Hüseyin KARADAĞ | Şamil SEFERGİL

The purpose of this study was to investigate the formation of the plexus sacralis in the Kyrgyz pheasant (Phasianus colchicus mongolicus) and the origin of the nerves emerging from the plexus sacralis. Five adult male Kyrgyz pheasants were used that had been hunted in their natural habitat near the town of Tokmok in the Chuy region of Kyrgyzstan. The plexus sacralis was found to be formed in the lumbar region by the ventral strands of sacral nerves 1 to 5, originating in the spinal cord. The plexus is composed of the truncus cranialis, which consists of the ventral strands of the first 3 nerve ...Более

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Cytochemistry of peripheral blood leukocytes in thoroughbred foals

Emrah SUR

We attempted to characterize the cytochemical staining patterns of leukocytes and to determine the percentages of alpha-naphthyl acetate esterase (ANAE) and acid phosphatase (ACPase) positive lymphocytes in peripheral blood of thoroughbred foals at different ages. Blood samples were obtained from the jugular veins of 60 healthy thoroughbred foals, 1 day, 3 days and 1 year old. Each age group included 10 male and 10 female animals. Peroxidase (PO) activity was detected in neutrophils, eosinophils and monocytes. Lymphocytes were negative for PO staining. Periodic acid-Schiff (PAS) staining was o ...Более

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Trace metal levels in edible wild fungi

Zeki SEVEROĞLU

Metal levels (cadmium, cobalt, chromium, copper, iron, nickel, lead and zinc) of seventeen different edible wild fungi species (Agaricus campestris, Calocybe gambosa, Coprinus comatus, Hericium coralloides, Hydnum repandum, H. repandum var. rufescens, Lactarius deliciosus, L. salminocolor, Macrolepiota procera, Pleurotus ostreatus, P. ostreatus var. columbinus, Ramaria aurea, R. stricta, Rhizopogon luteolus, Sparassis crispa, Suillus bovinus, Tricholoma terreum) growing in Bolu-Turkey were measured by inductively coupled plasma optical emission spectrocopy. The obtained data were analyzed with ...Более

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Electrochemically modified sulfisoxazole nanofilm on glassy carbon for determination of cadmium(II) in water samples

Ali Osman SOLAK

Sulfisoxazole (SO) was grafted to glassy carbon electrode (GCE) via the electrochemical oxidation of SO in acetonitrile solution containing 0.1 M tetrabutylammoniumtetra-fluoroborate (TBATFB). The prepared electrode was characterized by using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), reflection–absorption infrared spectroscopy (RAIRS) and X-ray photoelectron spectroscopy (XPS). The ellipsometric thickness of SO nanofilm at the glassy carbon surface was obtained as 14.48 ± 0.11 nm. The stability of the SO modified GCE was studied. The SO modified GCE was also utiliz ...Более

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A novel voltammetric sensor based on p-aminothiophenol functionalized graphene oxide/gold nanoparticles for determining quercetin in the presence of ascorbic acid

Ali Osman SOLAK

In this study, gold nanoparticles (AuNPs) with the diameters of maximum 25 nm were self-assembled onto the surfaces of p-aminothiophenol functionalized graphene oxide (ATPGO) sheets simply by mixing their aqueous dispersions. The prepared graphene oxide (GO), ATPGO and AuNPs–ATPGO composites were characterized by a transmission electron microscope (TEM), X-ray photoelectron spectroscopy (XPS), reflection–absorption infrared spectroscopy (RAIRS), the X-ray diffraction (XRD) method and Raman spectroscopy. The electrochemical determination of quercetin (QR) has been studied using square wave volt ...Более

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Surface characterization of dinitrophenyl-diaminophenyl nanoplatform on glassy carbon

Ali Osman SOLAK

2,4-dinitrophenol (DNP) was covalently bonded to glassy carbon substrate by cyclic voltammetry (CV) technique. 2, 4-diaminophenol film (DAPO) was acquired with electrochemical reduction of 2,4-dinitrophenol film (DNPO). Prepared films were characterized by X-ray photoelectron spectroscopy (XPS) and germanium attenuated total reflection infrared (GATR-FT-IR) spectroscopy. A hemispherical germanium ATR element used with p-polarized light at 65° incidence angle yielded high signal/noise IR spectra for monolayer coverage of molecules on glassy carbon substrate. Layer thickness of films was measure ...Более

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A novel sensitive Cu(II) and Cd(II) nanosensor platform: Graphene oxide terminated p-aminophenyl modified glassy carbon surface

Ali Osman SOLAK

Graphene oxide (GO) based glassy carbon (GC) electrode has been prepared. Firstly, p-nitrophenyl (NP) modified GC (NP/GC) electrode was prepared via the electrochemical reduction of its tetraflouroborate diazonium salt. After the formation of NP/GC electrode, the negative potential was applied to NP/GC electrode to reduce the nitro groups to amine. p-Aminophenyl (AP) modified GC (AP/GC) electrode was immersed into a graphene oxide solution containing 1-ethyl-3(3-(dimethlyamino)propyl)-carbodiimide. Hence, we constructed GO terminated AP modified GC (GO/AP/GC) electrode. NP/GC, AP/GC and GO/AP/ ...Более

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A novel impedimetric biosensor based on graphene oxide/gold nanoplatform for detection of DNA arrays

Ali Osman SOLAK

A highly sensitive method for detection of DNA hybridization was developed. This method was based on the modification of glassy carbon electrode with gold nanoparticles (AuNPs) involving p-aminothiophenol (ATP) functionalized graphene oxide (GO). This GO was used as a platform for impedimetric genosensing using 5′-TA GGG CCA CTT GGA CCT-(CH2)3-SH-3′ single-stranded probe (ss-DNA), 5′-AGG TCC AAG TGG CCC TA-3′ (target DNA), 5′-SH-C6-TAG GGC CA-3′ (non-complementary-1) and 5′-SH-C6-TGC CCG TTA CG 3-′ (non-complementary-2) oligonucleotide sequences. The film exhibited excellent properties for imm ...Более

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