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How does arsenic speciation (arsenite and arsenate) in groundwater affect the performance of an aerated electrocoagulation reactor and human health risk?

Mehmet KOBYA

Arsenic (As) occurrence in water resources has become one of the most critical environmental problems worldwide. The detrimental health impacts on humans have been reported due to the consumption of As-contaminated groundwater resources. Consumption of As-containing water over the long term can cause arsenicosis and chronic effects on human health due to its toxicity. Several treatment processes are available for As removals such as coagulation, ion exchange, adsorption, and membrane technologies but they have various major drawbacks. In the present work, therefore, an aerated electrocoagulati ...Более

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Graphene-based ZnCr layered double hydroxide nanocomposites as bactericidal agents with high sonophotocatalytic performances for degradation of rifampicin

Mehmet KOBYA

Herein, ZnCr layered double hydroxide (ZnCr LDH), and its nanocomposites with GO and rGO were synthesized using the co-precipitation method. The samples were characterized using XRD, FT-IR, SEM, TEM, BET, and XPS techniques. The sonophotocatalytic activity of the ZnCr LDH, ZnCr LDH/GO, and ZnCr LDH/rGO was investigated via the degradation of rifampicin (RIF) in the ultrasonic bath under visible light irradiation. The synergy index of more than 1 determined for ZnCr LDH/rGO indicated the positive interaction of sonocatalysis and photocatalysis resulted by hybridizing the LDH nanosheets with rGO ...Более

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Genetic diversity and population structure of apple germplasm from Eastern Black Sea region of Turkey by SSRs

Ahmet AYGÜN

Turkey has a diverse apple germplasm and Northeastern Anatolia had great contributions to domestication of the Malus genus. Despite quite high rainfall (900-2300 mm) and humidity (70-85?levels, several local apple cultivars have been successfully grown for centuries at the coastal zone of Eastern Black Sea region of Northeastern Anatolia without any pesticide applications. In this study, a set of 206 local genotypes, including 6 international cultivars as references was analyzed using 13 SSR primers with the aim of assessing the genetic diversity and population structure among the genotypes. B ...Более

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Synthesis and characterization of novel organo-hydrogel based agar, glycerol and peppermint oil as a natural drug carrier/release material

Nahit AKTAŞ

The very recent Covid-19 pandemic has made the need to understand biocompatible polymers as support material in drug delivery systems and controlled release clearer, especially for organo-hydrogels. This study aims to synthesize various new polymeric materials called gels, hydrogels, and organo-hydrogels according to the monomer used and to investigate their use as drug release systems. The agar-glycerol (AG) pair was used to synthesize the polymers, N, N, methylene bisacrylamide (MBA, m) and glutaraldehyde (GA, g) were used as cross-linkers and peppermint oil (PmO) was included to obtain the ...Более

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Arsenic removal from groundwater using an aerated electrocoagulation reactor with 3D Al electrodes in the presence of anions

Mehmet KOBYA

Co-occurrence of arsenic and anions in groundwater causes a severe health problems and combine effects of these pollutants significantly affect performance of treatment process. Thus, this study has been conducted to examine the combine effects of anions on arsenic removal using aerated electrocoagulation (EC) reactor with 3D Al electrodes in groundwater. A 3-level, six factors Box-Behnken experimental design (BBD) was applied to investigate the individual and combine effect of anions and operating time: phosphate (x(1): 1-10 mg L-1), silica (x(2): 20-80 mg L-1), bicarbonate (x(3): 130-670 mg ...Более

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A review on treatment of membrane concentrates generated from landfill leachate treatment processes

Mehmet KOBYA

Landfill leachate (LL) is highly toxic wastewater and comprises various pollutants such as organic compounds, biological organisms, xenobiotics, heavy metals, inorganic salts, and ammonia. The integration of conventional methods with membrane processes has become indispensable due to the enforcement of stricter regulations for the LL discharge. The integrated membrane technologies achieve a pollutant removal efficiency of higher than 95?ith a large volume of treated leachate and a low capital cost investment. However, the drawback of these processes is the production of a membrane concentrate ...Более

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Dichromate and arsenate anion removal by PEI microgel, cryogel, and bulkgel

Nahit AKTAŞ

Among the various metal ions, chromate (Cr(VI)) and arsenate (As(V)) are the two most hazardous toxic ion species and are found in nature in the form of dichromate and arsenate anions. In this investigation, polyethyleneimine (PEI)-based hydrogels were prepared with microgel, cryogel, and bulkgel morphologies employing glycerol diglycidyl ether as a crosslinker. The prepared PEI-based hydrogels were used to remove dichromate and arsenate anions from aqueous media. PEI microgel, cryogel, and bulkgels weighing 50 mg of each adsorbed 84.7 /- 0.8, 76.5 /- 5.2, and 108.9 /- 2.4 mg.g(-1) of dichroma ...Более

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Catalytic performance of boron-containing magnetic metal nanoparticles in methylene blue degradation reaction and mixture with other pollutants

Nahit AKTAŞ

The catalytic effects of metal nanoparticles (MNPs) synthesized in sodium bis(2-ethylhexyl) sulfosuccinate (AOT) microemulsion system by using M(II) salts (M = Fe, Co, Ni) and NaBH4 reducing agent on methylene blue (MB) degradation reaction were investigated. It was determined that Co-MNPs gave the best catalytic activity among them. Influence of the reaction parameters e.g., reaction time, temperature, the size of catalyst and the MNP types on the catalytic performance were studied. It was found that 37 /- 6 nm Co-MNPs revealed the best catalytic activity in all studies. The best activation p ...Более

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Interactive effects of salinity and drought stress on photosynthetic characteristics and physiology of tomato (Lycopersicon esculentum L.) seedlings

Atilla DURSUN

Sufficient quantity and quality of water are essential for vegetable production. Evaluating the individual and combined effects of drought and salt stress on plant establishment may help inform management of plant production in terms of stabilizing yield. This study investigates the effects of drought and salt stress on plant growth, nutrition elements, and select physiological parameters of tomato (Lycopersicon esculentum L. cv. H2274) through a pot experiment under greenhouse conditions. Drought stress was applied to tomato seedlings at 3 different levels of irrigation: D0 (control), D1, an ...Более

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Evaluation of textile wastewater treatment in sequential anaerobic moving bed bioreactor-aerobic membrane bioreactor

Mustafa DOLAZ

In this study, the treatability of real textile wastewater [dissolved organic carbon (DOC): 500 mg/L), color: 6383 Pt-Co, sulfate: 362 mg/L)] was investigated in sequential anaerobic moving bed bioreactor (AnMBBR) and aerobic membrane bioreactor (AeMBR). AnMBBR was filled with 40 % career material (Kaldnes K1). The effect of different hydraulic retention times (HRTs) (6-48 h) and powdered activated carbon (PAC) addition (1 g/L) was investigated for system optimization. Sequential AnMBBR- AeMBR was successfully operated for textile wastewater treatment corresponding to 92 %, and 90 % dissolved ...Более

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New formalism for characterization of simple non-reciprocal networks free from singularity-point problem

Mehmet ERTUĞRUL

A method has been proposed for accurate characterization of non-reciprocal networks without enforcing the passivity principle. Thanks to the introduced different even and odd coefficients, our method has no singularity-point problem as compared with the conventional method. The proposed method is validated by scattering parameter measurements of a ferrite-loaded waveguide shifter. In addition, it is demonstrated by measurements that our method, as compared with the conventional one, is more resistant to random noise due to post-calibration effects.

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