Arsenic (As) occurrence in water resources has become one of the most critical environmental problems worldwide. The detrimental health impacts on humans have been reported due to the consumption of As-contaminated groundwater resources. Consumption of As-containing water over the long term can cause arsenicosis and chronic effects on human health due to its toxicity. Several treatment processes are available for As removals such as coagulation, ion exchange, adsorption, and membrane technologies but they have various major drawbacks. In the present work, therefore, an aerated electrocoagulation (EC) system with aluminum anodes was operated for simultaneous arsenate (As(V)) and arsenite (As(III)) removal to overcome the disadvantages of other processes such as, sludge formation, difficulties in operation, high operating costs, high energy consumption, and the requirement of pre-treatment process and to enhance the conventional EC process. The combined effects of the applied current (0.075-0.3 A), aeration rate (0-61,/min), pH (6.5-8.5), and As speciation (As(V)-As(III)) were studied on As removal efficiency. The findings revealed that As removal mostly depended on the airflow rate and the applied current in the EC system. The highest As removal efficiency (99.1%) was obtained at an airflow rate of 6 L/min, a pH of 6.5, an initial As (V) concentration of 200 mu g/L, and a current of 0.3 A, with an energy consumption of 2.85 kWh/m(3) and an operating cost of 0.66 $/m(3). The human health risk assessment of treated water was also examined to understand the performance of the EC system. At most of the experimental runs, the chronic toxic risk (crR) and carcinogenic risk (CR) of As were within the permissible limits except for an airflow rate of 0-2 L/min, an initial pH of 8.5, and a current of 0.075-0.15 A for high initial As (III) concentrations. Overall, the As removal performance and groundwater risk assessment show that the EC process is a promising option for industrial applications.
Название публикации (dc.title) | How does arsenic speciation (arsenite and arsenate) in groundwater affect the performance of an aerated electrocoagulation reactor and human health risk? |
Автор/ы (dc.contributor.yazarlar) | Aysegül Yagmur Goren, Mehmet Kobya, Alireza Khataee |
Вид публикации (dc.type) | Makale |
Язык (dc.language) | İngilizce |
Год публикации (dc.date.issued) | 2021 |
Национальный/Международный (dc.identifier.ulusaluluslararasi) | Uluslararası |
Источник (dc.relation.journal) | Science of The Total Environment |
Том/№ (dc.identifier.volume) | 808 |
Страница (dc.identifier.startpage) | Article Number: 152135 |
ISSN/ISBN (dc.identifier.issn) | ISSN: 0048-9697; Online ISSN: 1879-1026 |
Издатель (dc.publisher) | Elsevier |
Базы данных (dc.contributor.veritaban) | Web of Science Core Collection |
Базы данных (dc.contributor.veritaban) | Sciencedirect |
Базы данных (dc.contributor.veritaban) | Scopus |
Вид индекса (dc.identifier.index) | SCI Expanded |
Вид индекса (dc.identifier.index) | Scopus |
Резюме (dc.description.abstract) | Arsenic (As) occurrence in water resources has become one of the most critical environmental problems worldwide. The detrimental health impacts on humans have been reported due to the consumption of As-contaminated groundwater resources. Consumption of As-containing water over the long term can cause arsenicosis and chronic effects on human health due to its toxicity. Several treatment processes are available for As removals such as coagulation, ion exchange, adsorption, and membrane technologies but they have various major drawbacks. In the present work, therefore, an aerated electrocoagulation (EC) system with aluminum anodes was operated for simultaneous arsenate (As(V)) and arsenite (As(III)) removal to overcome the disadvantages of other processes such as, sludge formation, difficulties in operation, high operating costs, high energy consumption, and the requirement of pre-treatment process and to enhance the conventional EC process. The combined effects of the applied current (0.075-0.3 A), aeration rate (0-61,/min), pH (6.5-8.5), and As speciation (As(V)-As(III)) were studied on As removal efficiency. The findings revealed that As removal mostly depended on the airflow rate and the applied current in the EC system. The highest As removal efficiency (99.1%) was obtained at an airflow rate of 6 L/min, a pH of 6.5, an initial As (V) concentration of 200 mu g/L, and a current of 0.3 A, with an energy consumption of 2.85 kWh/m(3) and an operating cost of 0.66 $/m(3). The human health risk assessment of treated water was also examined to understand the performance of the EC system. At most of the experimental runs, the chronic toxic risk (crR) and carcinogenic risk (CR) of As were within the permissible limits except for an airflow rate of 0-2 L/min, an initial pH of 8.5, and a current of 0.075-0.15 A for high initial As (III) concentrations. Overall, the As removal performance and groundwater risk assessment show that the EC process is a promising option for industrial applications. |
URL (dc.rights) | https://www.sciencedirect.com/science/article/abs/pii/S0048969721072119?via%3Dihub |
DOI (dc.identifier.doi) | 10.1016/j.scitotenv.2021.152135 |
Факультет / Институт (dc.identifier.fakulte) | Mühendislik Fakültesi |
Кафедра (dc.identifier.bolum) | Çevre Mühendisliği Bölümü |
Автор(ы) в учреждении (dc.contributor.author) | Mehmet KOBYA |
№ регистрации (dc.identifier.kayitno) | BL0FF699D9 |
Дата регистрации (dc.date.available) | 2022-02-07 |
Заметка (Год публикации) (dc.identifier.notyayinyili) | WOS Early Access: DEC 2021; Published: FEB 20 2022 |
Wos No (dc.identifier.wos) | WOS:000740227700012 |
Тематический рубрикатор (dc.subject) | arsenite |
Тематический рубрикатор (dc.subject) | arsenate |
Тематический рубрикатор (dc.subject) | groundwater |
Тематический рубрикатор (dc.subject) | electrocoagulation |
Тематический рубрикатор (dc.subject) | al balls |
Тематический рубрикатор (dc.subject) | health risk |