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Фильтры
Фильтры
Найденный: 26 Экземпляр 0.001 sn
Факультет / Институт [3]
Вид публикации [2]
Год публикации [6]
Язык [1]
Вид индекса [2]
Издатель [1]
Национальный/Международный [1]
Чистая вода и санитарные условияОбеспечение доступных для всех услуг по воде и водоотведению и обеспечение устойчивого управления водными ресурсами
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Ultrasound-assisted photocatalytic decomposition of rifadin with biochar and CNT-based NiCr layered double hydroxides

Mehmet KOBYA

Modification of layered double hydroxides (LDHs) is known to be beneficial for boosting the consistent formation of reactive oxygen species (ROSs) and enhancing the photocatalytic process. Herein, a facile synthesis method for preparing carbon nanotube (CNT) and biochar (BC)-based NiCr LDH (NC) nanocomposites as a sonophotocatalyst for the efficient degradation of rifadin (RA) was provided. The formation of thin nanosheet structures of NC along with porous and nanotube structures of BC and CNT was well approved by scanning electron microscope (SEM) and high-resolution transmission electron mic ...Более

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A techno-economical assessment of treatment by coagulation-flocculation with aluminum and iron-bases coagulants of landfill leachate membrane concentrates

Mehmet KOBYA

Landfill leachate treatment involved with the membrane bioreactor (MBR) combined with membrane treatment via nanofiltration (NF) and/or reverse osmosis (RO) is widely used in Turkey. This treatment produces landfill leachate membrane concentrates (LLMCs) with an undesirably high concentration of contaminants. In the study, two different nanofiltration concentrates of leachate were coagulated. Coagulant dosages from 0.10 to 5.0 g of Me3/L (Me3: Al3 or Fe3), and the pH values ranged from 4.0 to 8.0 and 3.0-9.0 for Al-based and Fe-based coagulants, respectively. The most efficient pH values were ...Более

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Perfluorooctanoic acid (PFOA) removal from real landfill leachate wastewater and simulated soil leachate by electrochemical oxidation process

Mehmet KOBYA

Poly and perfluoroalkyl compounds (PFASs) are a group of chemicals that are widely used and are difficult to purify. Within this group, perfluorooctanoic acid (PFOA), known for its highly polar and strong carbon-fluorine bonds, is a frequently encountered species in surface water, drinking water, and groundwater. In this study, we investigated the efficiency of electrooxidation (EO) in PFOA removal, optimization of EO parameters, and groundwater simulation in a realistic scenario. The EO optimization experiments were performed with a boron-doped diamond (BDD) anode for different values of pH, ...Более

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Synergistic effect of Fe and Co metals for the enhanced activation of hydrogen peroxide in the heterogeneous electro-Fenton process by Co-doped ZnFe layered double hydroxide

Mehmet KOBYA

Heterogeneous electro-Fenton (EF) is a powerful technology for the removal of emerging organic pollutants from wastewater. However, the development of catalysts with high activity towards the production of •OH by decomposing H2O2 remains a challenge. Herein, Co-doped ZnFe LDH as a heterogeneous catalyst with 2D plate-like morphology was produced by a co-precipitation method. Co-doping increased the pore volume of ZnFe LDH from 0.188 cm3/g to 0.2711 cm3/g and pore diameter from 5.305 nm and 9.39 nm. EF process consisted of a hydrothermally activated graphite felt cathode and a platinum plate an ...Более

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Tuned CuCr layered double hydroxide/carbon-based nanocomposites inducing sonophotocatalytic degradation of dimethyl phthalate

Mehmet KOBYA

This study is the first to explore the possibility of utilizing CuCr LDH decorated on reduced graphene oxide (rGO) and graphene oxide (GO) as sonophotocatalysts for the degradation of dimethyl phthalate (DMP). CuCr LDH and its nanocomposites were successfully fabricated and characterized. Scanning electron microscopy (SEM) along with high-resolution transmission electron microscope (HRTEM) both evidenced the formation of randomly oriented nanosheet structures of CuCr LDH coupled with thin and folded sheets of GO and rGO. The impact of diverse processes on the degradation efficiency of DMP in t ...Более

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Carbonaceous CoCr LDH nanocomposite as a light-responsive sonocatalyst for treatment of a plasticizer-containing water

Mehmet KOBYA

The carbonous-based nanocomposites of CoCr layered double hydroxide (LDH) with graphene oxide (GO) and reduced graphene oxide (rGO) were prepared. The successful synthesis of the CoCr LDH in hydrotalcite crystalline structure was deduced from the pattern obtained from X-ray diffraction, and the chemical composition of its surface was checked by X-ray photoelectron spectroscopy. The prosperous decorating of LDH on the sheets of rGO and GO was authenticated by the energy dispersive X-ray spectroscopy analysis and micrographs of scanning electron and transmission electron microscopy. The photo-as ...Более

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Electrochemical oxidation of perfluorooctanesulfonate (PFOS) from simulated soil leachate and landfill leachate concentrate

Mehmet KOBYA

The near-widespread presence of poly- and perfluoroalkyl substances (PFASs) in humans has generated concerns regarding the potential negative impact of these chemicals on human health, as some PFASs are exceedingly persistent and bioaccumulative. Among the perfluorinated PFASs, which exhibit high polarity and strong carbon–fluorine bonds, perfluorooctanesulfonate (PFOS) is one of the frequently encountered species. In this study, the efficiency of electrooxidation (EO) and its application in groundwater simulation were first evaluated as a realistic approach to PFOS removal. After optimizing E ...Более

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How does arsenic speciation (arsenite and arsenate) in groundwater affect the performance of an aerated electrocoagulation reactor and human health risk?

Mehmet KOBYA

Arsenic (As) occurrence in water resources has become one of the most critical environmental problems worldwide. The detrimental health impacts on humans have been reported due to the consumption of As-contaminated groundwater resources. Consumption of As-containing water over the long term can cause arsenicosis and chronic effects on human health due to its toxicity. Several treatment processes are available for As removals such as coagulation, ion exchange, adsorption, and membrane technologies but they have various major drawbacks. In the present work, therefore, an aerated electrocoagulati ...Более

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Zinc-chromium layered double hydroxides anchored on carbon nanotube and biochar for ultrasound-assisted photocatalysis of rifampicin

Mehmet KOBYA

In this study, ZnCr layered double hydroxide (LDH), ZnCr LDH/carbon nanotube (CNT), and ZnCr LDH/Biochar (BC) were synthesized and characterized by various analyses. The successful synthesis and the great crystallinity of the samples were consented by XRD analysis. SEM and TEM were applied to study the morphology of the synthesized samples. The simultaneous presence of C, Zn, and Cr elements was well confirmed by EDX and dot mapping analyses demonstrating the successful preparation of nanocomposites. According to the BET analysis, ZnCr LDH nanocomposites with BC and CNT had more specific surfa ...Более

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Removal of arsenic in groundwater from western Anatolia, Turkey using an electrocoagulation reactor with different types of iron anodes

Mehmet KOBYA | Mustafa DOLAZ

Electrocoagulation (EC) is a significantly efficient method for As removal from waters and received considerable attention recently. In this study, the natural groundwater (GW) samples containing As concentrations of GW-1: 538.8 mu g L-1, GW-2: 1132.1 mu g L-1, and GW-3: 52, 000 mu g L-1 were obtained from different provinces and treated by EC process using different iron anodes (plate, ball, and scrap). To achieve drinking water As standard (10 mu g L-1), the operational time, applied current, and As removal optimization for all anode types were studied. At applied current of 0.025 A, the As ...Более

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Synthesis of visible light responsive ZnCoFe layered double hydroxide towards enhanced photocatalytic activity in water treatment

Mehmet KOBYA

In this study, a ternary layered double hydroxide containing Zn, Co, and Fe transition metals (ZnCoFe LDH) was developed using a co-precipitation procedure. The as-synthesized photocatalyst was evaluated for its perfor-mance in the degradation of methylene blue (MB) under visible light irradiation. The effects of various process conditions including photocatalyst dosage, pollutant concentration, pH, lamp distance, and lamp power were investigated. The ZnCoFe LDH achieved approximately 74 photodegradation efficiency owing to the narrow bandgap of 2.14 eV. The Langmuir-Hinselwood rate constants ...Более

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Nanoarchitecture of graphene nanosheets decorated with NiCr layered double hydroxide for sonophotocatalytic degradation of refractory antibiotics

Mehmet KOBYA

Highly efficient and durable catalysts for wastewater treatment are urgently required to tackle critical environmental issues. In this regard, NiCr LDH (NC), NiCr LDH-GO (NC-GO), and NiCr LDH-rGO (NC-rGO) nanocomposites were synthesized. The results of XRD, EDX, and FTIR analyses not only explored the crystallographic and chemical structures of catalysts but also confirmed the successful synthesis. Further morphological, physical, chemical, and optical characteristics of the catalysts were evaluated more by SEM, HRTEM, BET, DRS, and XPS techniques. The as-synthesized catalysts were used for th ...Более

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