At present, titanium dioxide (TiO2)-supported CdTe photocatalysts were prepared by wet impregnation method for photocatalytic hydrogen peroxide (H2O2) electrooxidation. The structural and morphology surface analyses of these photocatalysts were characterized by X-Ray diffraction (XRD), scanning electron microscopy-energy dispersive X-Ray (SEM-EDX) and mapping analysis, high-resolution transmission electron microscopy (HR-TEM), ultraviolet–visible (UV–VIS) spectroscopy, X-ray photoelectron spectroscopy (XPS), and inductively coupled plasma mass spectrometry (ICP-MS). In addition, the photocatalytic activity of the photocatalysts was examined by cyclic voltammetry (CV). The CdTe(70–30)/TiO2 photocatalyst exhibited the best photocatalytic activity under UV illumination with a specific activity of 17.28 mA/cm2 both in the dark (7.86 mA/cm2) and compared to other photocatalysts. Furthermore, it was observed that it exhibited the best stability and resistance by chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) analyses. It could be a promising photoanode catalyst for photocatalytic fuel cells.
Keyword: electrooxidation; hydrogen peroxide; photocatalyst; photocatalytic fuel cell
Publication Name (dc.title) | The enhanced TiO2-supported CdTe photocatalysts for photocatalytic hydrogen peroxide electrooxidation |
Author/s (dc.contributor.yazarlar) | Aykut Caglar, Ayse Gözde Sayin, Nahit Aktas, Hilal Kivrak |
Publication type (dc.type) | Makale |
Language (dc.language) | İngilizce |
Publication year (dc.date.issued) | 2023 |
National/International (dc.identifier.ulusaluluslararasi) | Uluslararası |
Source (dc.relation.journal) | Journal of Photochemistry and Photobiology A: Chemistry |
Volume/Issue (dc.identifier.volume) | 445 |
Page (dc.identifier.startpage) | Article Number: 115070 |
ISSN/ISBN (dc.identifier.issn) | ISSN: 1010-6030; Online ISSN: 1873-2666 |
Publisher (dc.publisher) | Elsevier |
Databases (dc.contributor.veritaban) | Web of Science Core Collection |
Databases (dc.contributor.veritaban) | Sciencedirect |
Databases (dc.contributor.veritaban) | Scopus |
Index Type (dc.identifier.index) | SCI Expanded |
Index Type (dc.identifier.index) | Scopus |
Impact Factor (dc.identifier.etkifaktoru) | 4,3 / 2022-WOS / Son 5 yıl: 3,8 |
Abstract (dc.description.abstract) | At present, titanium dioxide (TiO2)-supported CdTe photocatalysts were prepared by wet impregnation method for photocatalytic hydrogen peroxide (H2O2) electrooxidation. The structural and morphology surface analyses of these photocatalysts were characterized by X-Ray diffraction (XRD), scanning electron microscopy-energy dispersive X-Ray (SEM-EDX) and mapping analysis, high-resolution transmission electron microscopy (HR-TEM), ultraviolet–visible (UV–VIS) spectroscopy, X-ray photoelectron spectroscopy (XPS), and inductively coupled plasma mass spectrometry (ICP-MS). In addition, the photocatalytic activity of the photocatalysts was examined by cyclic voltammetry (CV). The CdTe(70–30)/TiO2 photocatalyst exhibited the best photocatalytic activity under UV illumination with a specific activity of 17.28 mA/cm2 both in the dark (7.86 mA/cm2) and compared to other photocatalysts. Furthermore, it was observed that it exhibited the best stability and resistance by chronoamperometry (CA) and electrochemical impedance spectroscopy (EIS) analyses. It could be a promising photoanode catalyst for photocatalytic fuel cells. |
Abstract (dc.description.abstract) | Keyword: electrooxidation; hydrogen peroxide; photocatalyst; photocatalytic fuel cell |
URL (dc.rights) | https://www.sciencedirect.com/science/article/abs/pii/S101060302300535X |
DOI (dc.identifier.doi) | 10.1016/j.jphotochem.2023.115070 |
Faculty / Institute (dc.identifier.fakulte) | Mühendislik Fakültesi |
Department (dc.identifier.bolum) | Kimya Mühendisliği Bölümü |
Author(s) in the Institution (dc.contributor.author) | Nahit AKTAŞ |
Kayıt No (dc.identifier.kayitno) | BL9484714F |
Record Add Date (dc.date.available) | 2023-09-04 |
Notes (Publication year) (dc.identifier.notyayinyili) | November 2023 |
Wos No (dc.identifier.wos) | WOS:001091233000001 |
Subject Headings (dc.subject) | electrooxidation |
Subject Headings (dc.subject) | hydrogen peroxide |
Subject Headings (dc.subject) | photocatalyst |
Subject Headings (dc.subject) | photocatalytic fuel cell |