The reaction of N-(4-aminophenyl)aza-15-crown-5 (1) with anti-chlorophenylglyoxime (2) produces a novel azacrown ether containing vic-dioxime, N-(4-aminophenyl)aza-15-crown-5-phenylglyoxime (LH_2). LH_2 reacts with Ni(II), Cu(II), Co(II), Cd(II), and Zn(II) ions to yield the mononuclear transition and nontransition metal complexes [M(LH)_2] (M = Ni and Cu), [M(LH)_2(H_2O)_2] (M = Co), and [M(LH)(H_2O)(Cl)] (M = Cd and Zn). The structural features of LH_2 were studied using several techniques including elemental analysis, Fourier transform infrared spectroscopy (FT-IR), ultraviolet visible (UV-Vis), mass spectrometry (MS), 1-dimensional (1D) ^1H-NMR and ^{13}CNMR, distortionless enhancement by polarization transfer (DEPT) 2-dimensional (2D) heteronuclear single-quantum coherence (HSQC), and heteronuclear multiple-bond correlation (HMBC) techniques. The structures of the complexes were confirmed by elemental analyses and with the use of magnetic susceptibility measurements, MS, UV-Vis, FT-IR, ^1H-NMR, and ^{13}C-NMR techniques. The redox behaviors of the ligand and its complexes were verified with cyclic voltammetry (CV) at a glassy carbon (GC) electrode in 0.1 M tetrabutylammoniumtetrafluoroborate (TBATFB) in dimethyl sulfoxide (DMSO). -
Keywords: vic-Dioxime, azacrown ether, transition metal complexes, mass spectroscopy, cyclic voltammetry
Publication Name (dc.title) | Synthesis and structural and electrochemical characterization of novel macrocyclic vic-dioxime ligand and its mononuclear transition and nontransition metal complexes |
Author/s (dc.contributor.yazarlar) | Pervin DEVECİ, Bilge TANER, Zeynel KILIÇ, Ali OSMAN SOLAK, Emine ÖZCAN |
Publication type (dc.type) | Makale |
Language (dc.language) | İngilizce |
Publication year (dc.date.issued) | 2012 |
National/International (dc.identifier.ulusaluluslararasi) | Uluslararası |
Source (dc.relation.journal) | Turkish Journal of Chemistry |
Number (dc.identifier.issue) | 1 |
Volume/Issue (dc.identifier.volume) | 36 |
Page (dc.identifier.startpage) | 25-36 |
ISSN/ISBN (dc.identifier.issn) | ISSN: 1300-0527; Online ISSN: 1303-6130 |
Publisher (dc.publisher) | Tübitak |
Databases (dc.contributor.veritaban) | Web of Science Core Collection |
Databases (dc.contributor.veritaban) | Tübitak (Academik Journals) |
Databases (dc.contributor.veritaban) | Scopus |
Index Type (dc.identifier.index) | SCI Expanded |
Index Type (dc.identifier.index) | Scopus |
Impact Factor (dc.identifier.etkifaktoru) | 1,377 / 2017-WOS / 5 Year: 1,342 |
Abstract (dc.description.abstract) | The reaction of N-(4-aminophenyl)aza-15-crown-5 (1) with anti-chlorophenylglyoxime (2) produces a novel azacrown ether containing vic-dioxime, N-(4-aminophenyl)aza-15-crown-5-phenylglyoxime (LH_2). LH_2 reacts with Ni(II), Cu(II), Co(II), Cd(II), and Zn(II) ions to yield the mononuclear transition and nontransition metal complexes [M(LH)_2] (M = Ni and Cu), [M(LH)_2(H_2O)_2] (M = Co), and [M(LH)(H_2O)(Cl)] (M = Cd and Zn). The structural features of LH_2 were studied using several techniques including elemental analysis, Fourier transform infrared spectroscopy (FT-IR), ultraviolet visible (UV-Vis), mass spectrometry (MS), 1-dimensional (1D) ^1H-NMR and ^{13}CNMR, distortionless enhancement by polarization transfer (DEPT) 2-dimensional (2D) heteronuclear single-quantum coherence (HSQC), and heteronuclear multiple-bond correlation (HMBC) techniques. The structures of the complexes were confirmed by elemental analyses and with the use of magnetic susceptibility measurements, MS, UV-Vis, FT-IR, ^1H-NMR, and ^{13}C-NMR techniques. The redox behaviors of the ligand and its complexes were verified with cyclic voltammetry (CV) at a glassy carbon (GC) electrode in 0.1 M tetrabutylammoniumtetrafluoroborate (TBATFB) in dimethyl sulfoxide (DMSO). - |
Abstract (dc.description.abstract) | Keywords: vic-Dioxime, azacrown ether, transition metal complexes, mass spectroscopy, cyclic voltammetry |
URL (dc.rights) | https://journals.tubitak.gov.tr/chem/vol36/iss1/2/ |
DOI (dc.identifier.doi) | 10.3906/kim-1106-50 |
Faculty / Institute (dc.identifier.fakulte) | Mühendislik Fakültesi |
Department (dc.identifier.bolum) | Kimya Mühendisliği Bölümü |
Author(s) in the Institution (dc.contributor.author) | Ali Osman SOLAK |
Kayıt No (dc.identifier.kayitno) | BL2B9174B1 |
Record Add Date (dc.date.available) | 2016-03-18 |
Notes (Publication year) (dc.identifier.notyayinyili) | 2012 |
Wos No (dc.identifier.wos) | WOS:000300209600002 |
Subject Headings (dc.subject) | vic-dioxime |
Subject Headings (dc.subject) | azacrown ether |
Subject Headings (dc.subject) | transition metal complexes |
Subject Headings (dc.subject) | mass spectroscopy |
Subject Headings (dc.subject) | cyclic voltammetry |