In this study, 4-thiophenol modified glassy carbon electrode was prepared by the reduction of 4-diazothiophenol tetrafluoroborate salt. Silver nanoparticles were attached to the thiophenol modified surface to prepare a thiophenol-silver nanoparticle composite film. 4-Aminothiopenol molecules were deposited by self-assembling technique to form multi-layered nanofilms of TP/SNP/PhNH2 on glassy carbon substrate. These surfaces were characterized by cyclic voltammetry, electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy, reflectance-absorption infrared spectroscopy, and ellipsometry at each multilayer film growth process. Atomic force microscopic images of GC/TP/SNP/PhNH2 surfaces were also acquired. The characterization methods show that the amine group containing surface permits the subsequent modification by a variety of coupling reactions for the immobilization of more complex systems. An application of the electrode modification for the determination of uric acid with a significantly lower detection limit is described.
Yayın Adı (dc.title) | Synthesis, characterization, and application of silver nanoparticle-thiophenol nanocomposite film on the glassy carbon surface |
Yazar/lar (dc.contributor.yazarlar) | Remziye Güzel, Haslet Ekşi, Zafer Üstündağ, Ali Osman Solak |
Yayın Türü (dc.type) | Makale |
Dil (dc.language) | İngilizce |
Yayımlanma Yılı (dc.date.issued) | 2013 |
Ulusal/Uluslararası (dc.identifier.ulusaluluslararasi) | Uluslararası |
Kaynak (dc.relation.journal) | Surface and Interface Analysis |
Süreli Sayı (dc.identifier.issue) | 13 |
Cilt/Sayı (dc.identifier.volume) | 45 |
Sayfa (dc.identifier.startpage) | 1821–1829 |
ISSN/ISBN (dc.identifier.issn) | ISSN: 0142-2421; Online ISSN: 1096-9918 |
Yayıncı (dc.publisher) | Wiley |
Yayıncı (dc.publisher) | Blacwell |
Veri Tabanları (dc.contributor.veritaban) | Web of Science Core Collection |
Veri Tabanları (dc.contributor.veritaban) | Wiley |
Veri Tabanları (dc.contributor.veritaban) | Scopus |
İndex Türü (dc.identifier.index) | SCI Expanded |
İndex Türü (dc.identifier.index) | Scopus |
Etki Faktörü (dc.identifier.etkifaktoru) | 1,263 / 2017-WOS / 5 Year: 1,062 |
Özet (dc.description.abstract) | In this study, 4-thiophenol modified glassy carbon electrode was prepared by the reduction of 4-diazothiophenol tetrafluoroborate salt. Silver nanoparticles were attached to the thiophenol modified surface to prepare a thiophenol-silver nanoparticle composite film. 4-Aminothiopenol molecules were deposited by self-assembling technique to form multi-layered nanofilms of TP/SNP/PhNH2 on glassy carbon substrate. These surfaces were characterized by cyclic voltammetry, electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy, reflectance-absorption infrared spectroscopy, and ellipsometry at each multilayer film growth process. Atomic force microscopic images of GC/TP/SNP/PhNH2 surfaces were also acquired. The characterization methods show that the amine group containing surface permits the subsequent modification by a variety of coupling reactions for the immobilization of more complex systems. An application of the electrode modification for the determination of uric acid with a significantly lower detection limit is described. |
URL (dc.rights) | http://onlinelibrary.wiley.com/doi/10.1002/sia.5328/full |
DOI (dc.identifier.doi) | 10.1002/sia.5328 |
Fakültesi / Enstitütü (dc.identifier.fakulte) | Mühendislik Fakültesi |
Bölümü (dc.identifier.bolum) | Kimya Mühendisliği Bölümü |
Kurumdaki Yazar/lar (dc.contributor.author) | Ali Osman SOLAK |
Kayıt No (dc.identifier.kayitno) | BL9FCE1913 |
Kayıt Giriş Tarihi (dc.date.available) | 2016-03-16 |
Not (Yayımlanma Yılı) (dc.identifier.notyayinyili) | 7 October 2013 |
Wos No (dc.identifier.wos) | WOS:000330106700002 |
Konu Başlıkları (dc.subject) | diazonium salt |
Konu Başlıkları (dc.subject) | ellipsometry |
Konu Başlıkları (dc.subject) | glassy carbon |
Konu Başlıkları (dc.subject) | silver nanoparticles |
Konu Başlıkları (dc.subject) | surface characterization |
Konu Başlıkları (dc.subject) | thiophenol modification |
Konu Başlıkları (dc.subject) | uric acid |
Konu Başlıkları (dc.subject) | X-ray photoelectron spectroscopy |