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Prof. Dr. Nahit AKTAŞMühendislik Fakültesi
Doç. Dr. Hilal DEMİR KIVRAKMühendislik Fakültesi
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Carbon Nanotube Supported CdM(S, Se)/CdTe Anode Catalysts for Electrooxidation of Glucose in Alkaline Media

Hilal DEMİR KIVRAK | Nahit AKTAŞ

The sequential sodium borohydride (SBH, NaBH4) reduction method was utilized to prepare the 0.1 CdSe/CNT, 0.1 CdS/CNT, 0.1 (CdS-CNT)/CdTe, and 0.1 (CdSe-CNT)/CdTe catalysts. The XRD, SEM-EDS, TEM, and XPS analyses were used to characterize the catalysts. The electrochemical measurements were examined by cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS) analyses for glucose electrooxidation. The characterization analyses revealed that the desired structure was formed on the support material. The electrochemical analysis results indicated that the ...More

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Promoting formic acid and ethylene glycol electrooxidation activity on Ga modified Pd based catalysts

Hilal DEMİR KIVRAK | Nahit AKTAŞ

Herein, carbon nanotube (CNT)-supported Ga@PdAgCo catalysts were synthesized by sodium borohydride (SBH) sequential reduction method. These catalysts were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and inductively coupled plasma-mass spectrometry (ICP-MS). Characterization results revealed that these catalysts were succesfully preared at desired loading and atomic ratios. From the XRD pattern, the crystallite size of 0.5 Ga@PdAgCo(80:10:10)/CNT catalysts was found as 6.95 nm by utilizing the Scherrer equation. From ...More

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