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Prof. Dr. Nahit AKTAŞMühendislik Fakültesi
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Urea Uptake and Release by Novel Macrogels from Dimethylacrylamide

Nahit AKTAŞ

A novel macrogels poly(N,N-Dimethylacrylamide) (p(DMAAm)) and its derivatives were synthesized from DMAAm for use in urea uptake and release. p(DMAAm) surface was modified by NaOH and HCl to obtain p(DMAAm)/NaOH and p(DMAAm)/HCl, which are negatively and positively charged, respectively. The dynamic swelling behaviors, water retention and pH sensitivities of the macrogels were studied. It was found that all macrogels exhibited the equilibrium swelling ratio (SR) in the range 1068-1451%. Swelling kinetics showed that the macrogels possessed Fickian diffusion behavior while the diffusion coeffic ...More

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Boron-containing magnetic nanoparticles from Co, Ni, and Fe chloride salts and their catalytic performances on 4-nitrophenol reduction

Nahit AKTAŞ

In this study, magnetic metal nanoparticles (MNP) were prepared by using Fe, Co and Ni ions and NaBH4 as reducing agents in oil-in-water microemulsion system. The prepared MNP were used as catalyst in 4-Nitro phenol (4-NP) reduction to 4-Aminophenol (4-AP). It was found that magnetic Co MNP performed superior catalytic performances than Fe and Ni MNP for 4-NP reduction. The catalytic reduction experiments revealed that as the concentration of reducing agent, NaBH4 that was used in the preparation of Co MNP was increased, the complete conversion time for 4-NP to 4-AP was decreased as the sizes ...More

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