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Selective Electrochemical Determination of L-Cysteine by a Cobalt Carbon Nanotube (CNT)-Modified Glassy Carbon Electrode (GCE)

Nahit AKTAŞ

L-Cysteine is a semi-essential and proteinogenic amino acid, with the formula HO2CCH (NH2) CH2SH. L-cysteine is mostly found in protein-rich foods. In this study, catalysts consisting of cobalt (Co) supported on carbon nanotubes (CNTs) were prepared using the sodium borohydride (NaBH4) reduction method. These catalysts were characterized by means of energy-dispersive x-ray (EDX) with scanning electron microscopy (SEM), temperature-programmed reduction (TPR), and temperature-programmed oxidation (TPO) techniques. Characterization results confirmed the successful preparation of the desired catal ...More

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Electrochemically grafted etodolac film on glassy carbon for Pb(II) determination

Ali Osman SOLAK

This study reports the electrochemical modification of glassy carbon (GC) surface with etodolac (ETO), the characterization of this ETO modified glassy carbon (ETO/GC) electrode and its electroanalytical application for the determination of Pb(II) ions. Binding type of the etodolac with the glassy carbon surface was investigated and found that it was through the etheric linkage revealed from the reflection–absorption infrared spectroscopy (RAIRS). The ETO/GC electrode was characterized by cyclic voltammetry (CV), reflection–adsorption IR spectroscopy, electrochemical impedance spectroscopy (EI ...More

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Development of Nonenzymatic Benzoic Acid Detection on PdSn/GCE/Vulcan XC‐72R Prepared via Polyol Method

Nahit AKTAŞ

In this study a PdSn based sensor was developed for the determination of benzoic acid (BA) in foods. A carbon (Vulcan XC-72R) supported PdSn catalyst was prepared via polyol method and its surface electronic and chemical properties were investigated by advanced surface analytical techniques such as scanning electron microscopy (SEM), X-ray diffraction spectroscopy (XRD), X-ray Photoelectron Spectroscopy (XPS), temperature-programmed reduction with H-2 (TPR-H-2) and transmission electron microscopy (TEM). Electrochemical measurements were performed by employing cyclic voltammetry (CV) and diffe ...More

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Electrochemical Cysteine Sensor on Novel Ruthenium Based Ternary Catalyst

Nahit AKTAŞ

At present, a voltammetric L-Cystein (Cys) sensor is developed based on carbon nanotube (CNT) supported Ru-Mo-Pd trimetallic catalyst modified glassy carbon electrodes (GCE). Firstly, Ru-Mo/CNT catalysts are prepared via sodium borohydride reduction method and following this Ru-Mo/CNT modified GCE electrode is prepared and Pd electrodeposition at varying Pd concentrations is performed to obtain Ru-Mo-Pd/CNT catalysts. Ru-Mo-Pd/CNT catalyst is characterized by TEM and SEM-EDX. Characterization results reveal that Ru-Mo-Pd/CNT catalyst is succesfully synthesized. For electrochemical measurements ...More

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