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Databases : Sciencedirect ✕Department : Çevre Mühendisliği B ... ✕
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Ultrasound-assisted photocatalytic decomposition of rifadin with biochar and CNT-based NiCr layered double hydroxides

Mehmet KOBYA

Modification of layered double hydroxides (LDHs) is known to be beneficial for boosting the consistent formation of reactive oxygen species (ROSs) and enhancing the photocatalytic process. Herein, a facile synthesis method for preparing carbon nanotube (CNT) and biochar (BC)-based NiCr LDH (NC) nanocomposites as a sonophotocatalyst for the efficient degradation of rifadin (RA) was provided. The formation of thin nanosheet structures of NC along with porous and nanotube structures of BC and CNT was well approved by scanning electron microscope (SEM) and high-resolution transmission electron mic ...More

Article 2023 Mühendislik Fakültesi Surfaces and Interfaces36 54 Views
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A techno-economical assessment of treatment by coagulation-flocculation with aluminum and iron-bases coagulants of landfill leachate membrane concentrates

Mehmet KOBYA

Landfill leachate treatment involved with the membrane bioreactor (MBR) combined with membrane treatment via nanofiltration (NF) and/or reverse osmosis (RO) is widely used in Turkey. This treatment produces landfill leachate membrane concentrates (LLMCs) with an undesirably high concentration of contaminants. In the study, two different nanofiltration concentrates of leachate were coagulated. Coagulant dosages from 0.10 to 5.0 g of Me3/L (Me3: Al3 or Fe3), and the pH values ranged from 4.0 to 8.0 and 3.0-9.0 for Al-based and Fe-based coagulants, respectively. The most efficient pH values were ...More

Article 2023 Mühendislik Fakültesi Chemosphere314 75 Views
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Perfluorooctanoic acid (PFOA) removal from real landfill leachate wastewater and simulated soil leachate by electrochemical oxidation process

Mehmet KOBYA

Poly and perfluoroalkyl compounds (PFASs) are a group of chemicals that are widely used and are difficult to purify. Within this group, perfluorooctanoic acid (PFOA), known for its highly polar and strong carbon-fluorine bonds, is a frequently encountered species in surface water, drinking water, and groundwater. In this study, we investigated the efficiency of electrooxidation (EO) in PFOA removal, optimization of EO parameters, and groundwater simulation in a realistic scenario. The EO optimization experiments were performed with a boron-doped diamond (BDD) anode for different values of pH, ...More

Article 2022 Mühendislik Fakültesi Environmental Technology & Innovation28 46 Views
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Synergistic effect of Fe and Co metals for the enhanced activation of hydrogen peroxide in the heterogeneous electro-Fenton process by Co-doped ZnFe layered double hydroxide

Mehmet KOBYA

Heterogeneous electro-Fenton (EF) is a powerful technology for the removal of emerging organic pollutants from wastewater. However, the development of catalysts with high activity towards the production of •OH by decomposing H2O2 remains a challenge. Herein, Co-doped ZnFe LDH as a heterogeneous catalyst with 2D plate-like morphology was produced by a co-precipitation method. Co-doping increased the pore volume of ZnFe LDH from 0.188 cm3/g to 0.2711 cm3/g and pore diameter from 5.305 nm and 9.39 nm. EF process consisted of a hydrothermally activated graphite felt cathode and a platinum plate an ...More

Article 2022 Mühendislik Fakültesi Journal of Environmental Chemical Engineering10 ( 6 ) 69 Views
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Tuned CuCr layered double hydroxide/carbon-based nanocomposites inducing sonophotocatalytic degradation of dimethyl phthalate

Mehmet KOBYA

This study is the first to explore the possibility of utilizing CuCr LDH decorated on reduced graphene oxide (rGO) and graphene oxide (GO) as sonophotocatalysts for the degradation of dimethyl phthalate (DMP). CuCr LDH and its nanocomposites were successfully fabricated and characterized. Scanning electron microscopy (SEM) along with high-resolution transmission electron microscope (HRTEM) both evidenced the formation of randomly oriented nanosheet structures of CuCr LDH coupled with thin and folded sheets of GO and rGO. The impact of diverse processes on the degradation efficiency of DMP in t ...More

Article 2023 Mühendislik Fakültesi Ultrasonics Sonochemistry95 67 Views
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Carbonaceous CoCr LDH nanocomposite as a light-responsive sonocatalyst for treatment of a plasticizer-containing water

Mehmet KOBYA

The carbonous-based nanocomposites of CoCr layered double hydroxide (LDH) with graphene oxide (GO) and reduced graphene oxide (rGO) were prepared. The successful synthesis of the CoCr LDH in hydrotalcite crystalline structure was deduced from the pattern obtained from X-ray diffraction, and the chemical composition of its surface was checked by X-ray photoelectron spectroscopy. The prosperous decorating of LDH on the sheets of rGO and GO was authenticated by the energy dispersive X-ray spectroscopy analysis and micrographs of scanning electron and transmission electron microscopy. The photo-as ...More

Article 2023 Mühendislik Fakültesi Ultrasonics Sonochemistry98 43 Views
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Electrochemical oxidation of perfluorooctanesulfonate (PFOS) from simulated soil leachate and landfill leachate concentrate

Mehmet KOBYA

The near-widespread presence of poly- and perfluoroalkyl substances (PFASs) in humans has generated concerns regarding the potential negative impact of these chemicals on human health, as some PFASs are exceedingly persistent and bioaccumulative. Among the perfluorinated PFASs, which exhibit high polarity and strong carbon–fluorine bonds, perfluorooctanesulfonate (PFOS) is one of the frequently encountered species. In this study, the efficiency of electrooxidation (EO) and its application in groundwater simulation were first evaluated as a realistic approach to PFOS removal. After optimizing E ...More

Article 2023 Mühendislik Fakültesi Journal of Water Process Engineering56 11 Views
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Renewable-based treatment solution of Reactive Blue 21 dye on fly ash as low-cost and sustainable adsorbent

Mehmet KOBYA

This study investigated the removal of Reactive Blue 21 (RB 21) dye from aqueous solutions by adsorption, evaluating the waste fly ash (FA). The effects of the parameters, such as initial dye concentration (100–750 mg/L), initial pH (2.0–8.0), adsorbent dose (1.0–4.0 g/L), and temperature (298–323 K) on the adsorption process were investigated. The optimum initial pH value was 2.0 for the highest RB21 dye removal (75.2 mg/g). At optimized conditions (pH 2.0, an adsorbent dosage of 1.0 g/L, a dye concentration of 750 mg/L, and an equilibrium time of 72 h), the highest adsorption capacity was fo ...More

Article 2024 Mühendislik Fakültesi Journal of Chromatography A1715 14 Views
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Mixed metal oxide (Ru, Ir, Sn) electrodes in the anodic activation of peroxydisulfate for a sustainable degradation of rifampicin

Mehmet KOBYA

Electrochemical advanced oxidation processes (EAOPs) are promising approaches to wastewater purification. Anodic oxidation (AO), due to its ease and cost-efficiency, has attracted rising attention in this research area. Herein, we employ Mixed Metal Oxide (MMO) electrodes, including RuIrSnOx@Ti, RuIrOx@Ti, and RuOx@Ti, to activate peroxydisulfate (PDS) in the anodic activation process. The Rifampicin (RIF) pharmaceutical was selected as the model pollutant to be treated in the proposed electrochemical system. The surface and electrochemical characteristics of the electrodes were characterized ...More

Article 2024 Mühendislik Fakültesi Journal of Industrial and Engineering Chemistry ( Published online: 23 April 2024 ) 0 Views
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Nutritional composition of ghee of various animal origins produced in some silk road countries

Canıl İSKAKOVA

This study aimed to investigate the fatty acids, vitamins, and minerals of ghee from various animal milk from different countries, such as India, Kazakhstan, Kyrgyzstan, Mongolia, and Turkey. Ghee consists of 98.9 of fat, irrespective of the animal source. Among the short- and medium-chain saturated fatty acids, all samples contain butyric (C4:0), caproic (C6:0), caprylic (C8:0), and capric acid (C10:0). Mare and goat ghee additionally contain undecanoic acid (C11:0). Major fatty acids were myristic acid (C14:0), palmitic acid (C16:0), stearic acid (C18:0), and monounsaturated fatty acid was o ...More

Article 2024 Mühendislik Fakültesi Journal of Food Composition and Analysis132 2 Views
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How does arsenic speciation (arsenite and arsenate) in groundwater affect the performance of an aerated electrocoagulation reactor and human health risk?

Mehmet KOBYA

Arsenic (As) occurrence in water resources has become one of the most critical environmental problems worldwide. The detrimental health impacts on humans have been reported due to the consumption of As-contaminated groundwater resources. Consumption of As-containing water over the long term can cause arsenicosis and chronic effects on human health due to its toxicity. Several treatment processes are available for As removals such as coagulation, ion exchange, adsorption, and membrane technologies but they have various major drawbacks. In the present work, therefore, an aerated electrocoagulati ...More

Article 2021 Mühendislik Fakültesi Science of The Total Environment808 50 Views
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Zinc-chromium layered double hydroxides anchored on carbon nanotube and biochar for ultrasound-assisted photocatalysis of rifampicin

Mehmet KOBYA

In this study, ZnCr layered double hydroxide (LDH), ZnCr LDH/carbon nanotube (CNT), and ZnCr LDH/Biochar (BC) were synthesized and characterized by various analyses. The successful synthesis and the great crystallinity of the samples were consented by XRD analysis. SEM and TEM were applied to study the morphology of the synthesized samples. The simultaneous presence of C, Zn, and Cr elements was well confirmed by EDX and dot mapping analyses demonstrating the successful preparation of nanocomposites. According to the BET analysis, ZnCr LDH nanocomposites with BC and CNT had more specific surfa ...More

Article 2022 Mühendislik Fakültesi Ultrasonics Sonochemistry82 54 Views
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