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Prof. Dr. Mustafa DOLAZMühendislik Fakültesi
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Concentration Distribution of Molecules and Other Species in the Model System Fe-NaCl-Na2S-H2SO4-H2O at Various Temperatures of the Electrocoagulation Process

Zarlık MAYMEKOV | Canarbek İZAKOV | Nurzat ŞAYKİYEVA | Mustafa DOLAZ | Mehmet KOBYA

Under practical conditions, one of the possible solutions to the problem of treatment of hydrogen-sulfide-containing industrial wastewater is the electrochemical oxidation of sulfides. In this work, the model system Fe-NaCl-Na2S-H2SO4-H2O is considered, an experimental setup is constructed, and the electrocoagulation process is studied in a wide (288-308 K) range of temperatures of an aqueous solution of hydrogen sulfide. The optimal ratios between the initial components in the system are determined. The experimental and calculated pH of the solution are found. The system is thermodynamically ...More

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Electrochemical Sulfur Removal at Controlled and Uncontrolled pHs with an Iron Anode

Nurzat ŞAYKİYEVA | Mustafa DOLAZ | Zarlık MAYMEKOV | Mehmet KOBYA

In this study, sulfide removal was carried out in the Electrocoagulation process under controlled and uncontrolled pH conditions. Under optimum conditions, electrocoagulation took place in less than 40 minutes at uncontrolled pH and less than 30 minutes at controlled pH to reduce the sulfite concentration of the effluent below 0.5 mg/L. The reaction rate constant and iron-sulfide molar ratio for sulfide removal were 14.09 x 10(-2) min(-1) and 0.97 mol/mol, respectively; under uncontrolled pH conditions, they were 22.88 x 10(-2) and 0.97 mol/mol at controlled pH. The mg sulfide removed per g Fe ...More

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10XSBF Bone-Like Hydroxyapatite Coating of Ti-6Al-4V with Microwave Irradiation and its Antibacterial Properties

Mustafa DOLAZ

The surfaces of titanium (Ti-6Al-4V) implants, which are widely preferred as implant material in medicine and dentistry, are biomimetically coated with nanohydroxyapatite (nHAp) in simulated body fluid (10XSBF) with microwave-assisted 10-f time concentration solution. A second layer was formed with different amounts of non-toxic AgNO3 to impart antibacterial properties to the implant materials coated with nHAp. In comparison of uncoated implants with nHAp and Ag-coated Ti-6Al-4V implants, surface morphologies were evaluated by SEM analysis, phase grade and structure were evaluated by XRD, and ...More

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Synthesis and Characterization of Hydroxypropyl Acorn Starch (HPAS) From Oak Acorn

Mustafa DOLAZ

The utilization of forest auxiliary products and their conversion into products with higher added value is important for the use of renewable resources. For this purpose, acorns belonging to the Q. coccifera species were collected in November, which is their ripening period, and dried and ground in the laboratory. Then, acorn starch (AS) was isolated from the sieved acorn flour. For 5 g of this isolated AS, hydroxypropyl acorn starch (HPAS) with the highest molar substitution (MS = 0.319) was synthesized by optimizing at 45 degrees C for 5 h with 30 g of propylene oxide and 1.88 g of NaOH. The ...More

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Synthesis and Characterization of Hydroxyethyl Starch from Chips Wastes Under Microwave Irradiation

Mustafa DOLAZ

This article focuses on the synthesis of hydroxyethyl potato starch (HEPS) for liquid hand soap by evaluating waste potato starch (WPS), a byproduct in potato chips production. It is a cheap, biodegradable, non-toxic and renewable natural polymer, available in great quantities on a global level. In a factory producing potato chips, WPS, which remained in the aqueous medium during peeling, slicing, and washing the potatoes, was purified at the desired temperature with H2O2 and NaOH. HEPSs with the molar substitution (MS) in the range from 0.298 to 0.670, were synthesized under microwave irradia ...More

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