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Ultrasound-assisted photocatalytic decomposition of rifadin with biochar and CNT-based NiCr layered double hydroxides

Mehmet KOBYA

Modification of layered double hydroxides (LDHs) is known to be beneficial for boosting the consistent formation of reactive oxygen species (ROSs) and enhancing the photocatalytic process. Herein, a facile synthesis method for preparing carbon nanotube (CNT) and biochar (BC)-based NiCr LDH (NC) nanocomposites as a sonophotocatalyst for the efficient degradation of rifadin (RA) was provided. The formation of thin nanosheet structures of NC along with porous and nanotube structures of BC and CNT was well approved by scanning electron microscope (SEM) and high-resolution transmission electron mic ...More

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A techno-economical assessment of treatment by coagulation-flocculation with aluminum and iron-bases coagulants of landfill leachate membrane concentrates

Mehmet KOBYA

Landfill leachate treatment involved with the membrane bioreactor (MBR) combined with membrane treatment via nanofiltration (NF) and/or reverse osmosis (RO) is widely used in Turkey. This treatment produces landfill leachate membrane concentrates (LLMCs) with an undesirably high concentration of contaminants. In the study, two different nanofiltration concentrates of leachate were coagulated. Coagulant dosages from 0.10 to 5.0 g of Me3/L (Me3: Al3 or Fe3), and the pH values ranged from 4.0 to 8.0 and 3.0-9.0 for Al-based and Fe-based coagulants, respectively. The most efficient pH values were ...More

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Perfluorooctanoic acid (PFOA) removal from real landfill leachate wastewater and simulated soil leachate by electrochemical oxidation process

Mehmet KOBYA

Poly and perfluoroalkyl compounds (PFASs) are a group of chemicals that are widely used and are difficult to purify. Within this group, perfluorooctanoic acid (PFOA), known for its highly polar and strong carbon-fluorine bonds, is a frequently encountered species in surface water, drinking water, and groundwater. In this study, we investigated the efficiency of electrooxidation (EO) in PFOA removal, optimization of EO parameters, and groundwater simulation in a realistic scenario. The EO optimization experiments were performed with a boron-doped diamond (BDD) anode for different values of pH, ...More

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Effects of botanical gardens on student environmental perception

Hasan YILMAZ

This paper examines the role of the classroom environment in promoting student well-being and, more specif-ically, a sense of responsibility towards nature in the city. The study analyzed how indoor vs outdoor educational environments affect students' perception of events and phenomena focusing on emotional, behavioral and cognitive processes. It was conducted in the Kayakyolu Secondary School, Erzurum, Turkey with 282 students ranging in age from 11 to 14 in grades 5-8. They participated in reading a story in two distinct environments: an enclosed indoor classroom and an outdoor botanical gar ...More

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Effect of delamination size, location and boundary conditions on the behavior of a laminated glass plate

Ebru DURAL

Laminated glass is made by combining glass layers with polyvinyl butyral (PVB) or a different adhesive with the help of heat and pressure. Its popularity is increasing in the building industry as a protective material. However, despite the popularity of laminated glass as a structural material, delamination is recognized as a highly undesirable problem inducing major damage to laminated glass. The effect of boundary conditions on the delamination strength of laminated glass is observed in this study. It is concluded that the location and size of delamination have a considerable effect in deter ...More

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Synergistic effect of Fe and Co metals for the enhanced activation of hydrogen peroxide in the heterogeneous electro-Fenton process by Co-doped ZnFe layered double hydroxide

Mehmet KOBYA

Heterogeneous electro-Fenton (EF) is a powerful technology for the removal of emerging organic pollutants from wastewater. However, the development of catalysts with high activity towards the production of •OH by decomposing H2O2 remains a challenge. Herein, Co-doped ZnFe LDH as a heterogeneous catalyst with 2D plate-like morphology was produced by a co-precipitation method. Co-doping increased the pore volume of ZnFe LDH from 0.188 cm3/g to 0.2711 cm3/g and pore diameter from 5.305 nm and 9.39 nm. EF process consisted of a hydrothermally activated graphite felt cathode and a platinum plate an ...More

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The relationship between long-term portfolio investments and growth in the context of asset characteristics and development level

İbrahim Halil SUGÖZÜ

This study investigates the linkage between portfolio investment and economic growth in 18 developed and 27 developing countries. Furthermore, it compares and analyzes interest-bearing and non-interest-bearing assets and the economic development level. The results of our analysis show that long-term portfolio investment is positively associated with economic growth in developing countries. Long-term portfolio investment through non-interest-bearing assets contribute more to economic growth in developing countries. However, stocks and long-term bond portfolio investment are unrelated to economi ...More

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A novel carbohydrate antigen 125 electrochemical sensor based on sweet almond oil organo-hydrogels

Nahit AKTAŞ

Ovarian cancer is a gynecological disease causing many deaths among women around the world. Carbohydrate antigen 125 (CA-125) is a single biomarker known to be a tumor marker of ovarian cancer. CA-125 is widely used to monitor the treatment process, recurrences, and for the detection of ovarian cancer. Herein, organo-hydrogels were prepared in order to detect CA-125 sensitively in serum medium with electrochemical methods. Organo-hydrogels were obtained by the free radical polymerization reaction using agar and glycerol with varying proportions of sweet almond oil using methylene bisacrylamide ...More

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Tuned CuCr layered double hydroxide/carbon-based nanocomposites inducing sonophotocatalytic degradation of dimethyl phthalate

Mehmet KOBYA

This study is the first to explore the possibility of utilizing CuCr LDH decorated on reduced graphene oxide (rGO) and graphene oxide (GO) as sonophotocatalysts for the degradation of dimethyl phthalate (DMP). CuCr LDH and its nanocomposites were successfully fabricated and characterized. Scanning electron microscopy (SEM) along with high-resolution transmission electron microscope (HRTEM) both evidenced the formation of randomly oriented nanosheet structures of CuCr LDH coupled with thin and folded sheets of GO and rGO. The impact of diverse processes on the degradation efficiency of DMP in t ...More

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Fejér-type positive operator based on Takenaka-Malmquist system on unit circle

Fahreddin ABDULLAYEV

Let φ={φk}k=−∞∞ denote the extended Takenaka–Malmquist system on unit circle T and let σn,φ(f), f∈L1(T), be the Fejér-type operator based on φ, introduced by V. N. Rusak. We give the convergence criteria for σn,φ(f) in Banach space C(T). Also we prove the Voronovskaya-type theorem for σn,φ(f) on class of holomorphic functions representable by Cauchy-type integrals with bounded densities. Keywords: Holomorphic functions; Takenaka–Malmquist system; Fejér type operator; Blaschke product; Frostman condition

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Reducing oxidative stress by kappa-carrageenan and C60HyFn: The post-thaw quality and antioxidant status of Azari water buffalo bull semen

Damla ARSLAN ACARÖZ

Azeri water buffalo is a species of great interest due to the high quality of its products such as milk. Due to the decreasing trend of its number and risk of extinction in the future, our attention is directed towards ensuring the preservation of its genetic reserves by keeping its sperm. Using antioxidants in semen extender is one of the ways to reduce the detrimental effects of freezing process on post-thawed quality of spermatozoa. This study was conducted to determine the effect of κ-carrageenan (k-CRG) and C60HyFn supplemented semen extender on the quality of post-thawed Azari water buff ...More

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Carbonaceous CoCr LDH nanocomposite as a light-responsive sonocatalyst for treatment of a plasticizer-containing water

Mehmet KOBYA

The carbonous-based nanocomposites of CoCr layered double hydroxide (LDH) with graphene oxide (GO) and reduced graphene oxide (rGO) were prepared. The successful synthesis of the CoCr LDH in hydrotalcite crystalline structure was deduced from the pattern obtained from X-ray diffraction, and the chemical composition of its surface was checked by X-ray photoelectron spectroscopy. The prosperous decorating of LDH on the sheets of rGO and GO was authenticated by the energy dispersive X-ray spectroscopy analysis and micrographs of scanning electron and transmission electron microscopy. The photo-as ...More

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