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Zarlık MAYMEKOV | Canarbek İZAKOV | Nurzat ŞAYKİYEVA | Mustafa DOLAZ | Mehmet KOBYA
В практических условиях одним из возможных решений проблемы очистки сероводородсодержащих промышленных сточных вод является электрохимическое окисление сульфидов. С учетом этих обстоятельств, в работе рассмотрена модельная система Fe–NaCl–Na2S–H2SO4–H2O, собрана экспериментальная установка и изучен процесс электрокоагуляции в широких пределах изменения температуры (288–308 К) водного раствора сероводорода. Выявлены оптимальные соотношения исходных компонентов в системе. Определены экспериментальные и расчетные водородные показатели раствора (pH). Осуществлено термодинамическое моделирование си ...More
Zarlık MAYMEKOV | Canarbek İZAKOV | Nurzat ŞAYKİYEVA | Mustafa DOLAZ | Mehmet KOBYA
Under practical conditions, one of the possible solutions to the problem of treatment of hydrogen-sulfide-containing industrial wastewater is the electrochemical oxidation of sulfides. In this work, the model system Fe-NaCl-Na2S-H2SO4-H2O is considered, an experimental setup is constructed, and the electrocoagulation process is studied in a wide (288-308 K) range of temperatures of an aqueous solution of hydrogen sulfide. The optimal ratios between the initial components in the system are determined. The experimental and calculated pH of the solution are found. The system is thermodynamically ...More
In this study, thermodynamic modelling of the process of thermal destruction of oil-contaminated soil of Ozenmunaigas JSC, which includes compounds such as carbon, silicon, aluminum, iron, calcium, magnesium, sodium, potassium, chromium, phosphorus, manganese, copper, titanium, molybdenum, nickel, vanadium, and water, was carried out. The physicochemical and thermodynamic parameters of the complex system were calculated at P0.1 MPa, T598-3000 K. The concentration distribution of components, particles, and condensed phases in the gas phase has been established. In the process of thermal destruc ...More
С целью прогнозирования и оценки величины углеродного следа в газовой фазе изучен процесс окисление мазута в избытке воздуха (альфа-фактор 1.3) в широких пределах изменения температуры (T 298–3000 К, Р 0.1 МПа). Рассчитаны равновесные термодинамические параметры (энтропия, энтальпия и внутренняя энергия) и определены концентрационные распределения С, S, N, O, H – содержащих компонентов и активных частиц в газовой фазе. На основе суммарного концентрационного распределения С, S, N, O, H – содержащих компонентов и активных частиц в газовой фазе рассчитано весовое содержание углерода. С учетом хим ...More
To predict and evaluate the carbon footprint in the gas phase, furnace fuel oil oxidation in excess air (alpha factor 1.3) was studied over a wide temperature (T 298–3000 K, P 0.1 MPa). Equilibrium thermodynamic parameters (entropy, enthalpy, and internal energy) and the concentration distributions of C-, S-, N-, O-, and H-containing components and active particles in the gas phase were determined. Based on the total concentration distribution of C-, S-, N-, O-, and H-containing components and active particles in the gas phase, the weight content of carbon was calculated. Taking into account t ...More
Nurzat ŞAYKİYEVA | Mustafa DOLAZ | Zarlık MAYMEKOV | Mehmet KOBYA
In this study, sulfide removal was carried out in the Electrocoagulation process under controlled and uncontrolled pH conditions. Under optimum conditions, electrocoagulation took place in less than 40 minutes at uncontrolled pH and less than 30 minutes at controlled pH to reduce the sulfite concentration of the effluent below 0.5 mg/L. The reaction rate constant and iron-sulfide molar ratio for sulfide removal were 14.09 x 10(-2) min(-1) and 0.97 mol/mol, respectively; under uncontrolled pH conditions, they were 22.88 x 10(-2) and 0.97 mol/mol at controlled pH. The mg sulfide removed per g Fe ...More