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Found: 11 Piece 0.001 sn
UN Sustainable Development : Clean water and sani ... ✕Department : Kimya Mühendisliği B ... ✕
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Clean water and sanitationEnsure access to water and sanitation for all and sustainable water management
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The efficiency of cationic-based hydrogels in heavy metal removal from wastewater

Bakıt BORKOYEV | Kalıypa SALİYEVA

The present study draws attention to arsenic (V) (As(V)), chromium (III) (Cr(III)), and chromium (VI) (Cr(VI)) heavy metal pollutants, which have negative effects on aquatic ecosystems and indirectly pose a serious threat to the health of living things in the environment. Homopolymer and copolymer hydrogels were synthesized by the UV polymerization technique using 2-acrylamido-2-methyl-1-propansulfonic acid sodium salt (AMPS) and 3-acrlylamidopropil-trimethyl ammonium chloride monomers, and a crosslinker aimed to improve the swelling properties and metal sorption of the prepared hydrogels. The ...More

Article 2023 Mühendislik Fakültesi Polymer Bulletin81 ( 8 ) 31 Views
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pH-Responsive Amphoteric p (APTMACl-co-AMPS) Hydrogel as Effective Multiple Dye Sponge Network From Aqueous Media

Nahit AKTAŞ

Here, the cationic poly (3-acrylamidepropyl trimethyl ammonium chloride) [p (APTMACl)], anionic poly (2-acrylamido-2methylpropane sulfonic acid) [p (AMPS)], and amphoteric poly (APTMACl-co-AMPS) hydrogels were prepared via free-radical polymerization techniques as pH-sensitive hydrogels. The prepared systems were used in methylene blue (MB), and Eosin Y (EY) removal from aqueous media. HCl-treated p (APTMACl-co-AMPS) hydrogels prepared in 1:3 mol ratio adsorbed higher amount of MB and EY from their corresponding 50 ml 50 ppm aqueous solutions that are 47.5 /- 0.9, and 10.7 /- 0.1 mg/g, respect ...More

Article 2022 Mühendislik Fakültesi Frontiers in Materials9 87 Views
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Activated Carbon for Wastewater Treatment from Phenol Compounds

Külümkan SARTOVA | Emil ÖMÜRZAK

Application of activated carbon (AC) obtained from cotton wastes (bolls, stems, and roots) for phenol adsorp-tion from water, or wastewater dephenolization, is presented. The kinetics of phenol adsorption by carbon adsor-bents were studied using UV/Vis spectrophotometer. The porosity of the formed ACs ranged from 1.952 to 2.339 cm3/g, the volume of macropores was from 1.79 to 2.09 cm3/g, while the commercial sample BAU-A showed 1.920 and 1.320 cm3/g, respectively. The highest phenol adsorption rate, 32.49-52.80 mg/(g center dot min), was observed for contact time up to 5 min on carbon adsorben ...More

Article 2022 Mühendislik Fakültesi Chemistry for Sustainable Development30 ( 3 ) 13 Views
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Activated carbon obtained from the cotton processing wastes

Külümkan SARTOVA | Emil ÖMÜRZAK | Bakıt BORKOYEV

Activated carbon (AC) was obtained from the cotton (Gossypium malvaceae) processing waste materials. The process was carried out by carbonization at 500–800 °C and subsequent activation at 800 °C by water stream. Cotton biomass is a renewable, low-cost alternative source for textile and food products; however, it hasn't been used for manufacturing of an activated carbon by carbonization in a boiling layer method. Characterization of adsorbents by means of Scanning Electronic Microscope and FT-IR showed that high porosity of carbonized products which was achieved and functional groups were form ...More

Article 2019 Mühendislik Fakültesi Diamond and Related Materials91 180 Views
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Thermal and Optical Properties of In and In2O3 Nanoparticles Synthesized Using Pulsed Plasma in Water

Emil ÖMÜRZAK

We present small indium (In) nanoparticles with an average diameter of 4.5 nm synthesized by pulsed plasma in water. Slightly increased lattice constants and thermal stability of the tetragonal In are revealed by X‐ray diffraction analysis, Rietveld refinement, and thermogravimetric analysis. The highly crystalline body‐centered cubic indium oxide (In2O3) nanoparticles with an average diameter of 12 nm and various shapes (semispherical, semihexagonal, and semicubic) are obtained by annealing the as‐synthesized In nanoparticles at 450 °C. The bandgap energy of the In2O3 nanoparticles is 3.63 eV ...More

Article 2018 Mühendislik Fakültesi Physica Status Solidi (A) – Applications and Materials Science215 ( 11 ) 65 Views
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Dichromate and arsenate anion removal by PEI microgel, cryogel, and bulkgel

Nahit AKTAŞ

Among the various metal ions, chromate (Cr(VI)) and arsenate (As(V)) are the two most hazardous toxic ion species and are found in nature in the form of dichromate and arsenate anions. In this investigation, polyethyleneimine (PEI)-based hydrogels were prepared with microgel, cryogel, and bulkgel morphologies employing glycerol diglycidyl ether as a crosslinker. The prepared PEI-based hydrogels were used to remove dichromate and arsenate anions from aqueous media. PEI microgel, cryogel, and bulkgels weighing 50 mg of each adsorbed 84.7 /- 0.8, 76.5 /- 5.2, and 108.9 /- 2.4 mg.g(-1) of dichroma ...More

Article 2021 Mühendislik Fakültesi Journal of Environmental Chemical Engineering9 ( 2 ) 92 Views
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Catalytic performance of boron-containing magnetic metal nanoparticles in methylene blue degradation reaction and mixture with other pollutants

Nahit AKTAŞ

The catalytic effects of metal nanoparticles (MNPs) synthesized in sodium bis(2-ethylhexyl) sulfosuccinate (AOT) microemulsion system by using M(II) salts (M = Fe, Co, Ni) and NaBH4 reducing agent on methylene blue (MB) degradation reaction were investigated. It was determined that Co-MNPs gave the best catalytic activity among them. Influence of the reaction parameters e.g., reaction time, temperature, the size of catalyst and the MNP types on the catalytic performance were studied. It was found that 37 /- 6 nm Co-MNPs revealed the best catalytic activity in all studies. The best activation p ...More

Article 2021 Mühendislik Fakültesi Inorganic Chemistry Communications126 72 Views
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Superabsorbent hydrogels based on N,N-dimethylacrylamide and maleic acid for applications in agriculture as water purifier and nitrogen carrier

Nahit AKTAŞ

To reduce water pollution caused by fertilizers in agricultural irrigation, highly swelling crosslinked hydrogels (p(DMAAm-co-MA) or DM1) based on N,N-dimethylacrylamide (DMAAm) and maleic acid (MA) were prepared using a chemical initiator with the redox polymerization technique. Negative and positive surface modifications of DM1 were achieved using hydrochloric acid (HCl) (p(DMAAm-co-MA)/HCl or DM2) and sodium hydroxide (NaOH) (p(DMAAm-co-MA)/NaOH or DM3), respectively. The synthesized hydrogels were named DM1, DM2 and DM3, respectively. The swelling properties, urea sorption and urea release ...More

Article 2021 Mühendislik Fakültesi Polymer Bulletin79 ( 10 ) 96 Views
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Quantum size effect of cadmium-doped titanium dioxide photocatalysts towards methylene blue degradation and electrooxidation

Nahit AKTAŞ

At present, titanium dioxide supported cadmium catalysts were prepared at 0.5-5?admium loading by impregnation method. 0.5?d/TiO2 catalyst was characterized with scanning electron microscopy-energy dispersive X-ray (SEM-EDX), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). Characterization results revealed that by cadmium doping to titanium dioxide, surface electronic properties and crystal structure of Cd/TiO2 catalysts changed as obtained from SEM-EDX, XRD, and XPS. Following this, methylene blue degradation and electrochemical oxidation measurements were examined under ...More

Article 2021 Mühendislik Fakültesi International Journal of Environmental Science and Technology (IJEST)19 ( 10 ) 55 Views
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Boron-containing magnetic nanoparticles from Co, Ni, and Fe chloride salts and their catalytic performances on 4-nitrophenol reduction

Nahit AKTAŞ

In this study, magnetic metal nanoparticles (MNP) were prepared by using Fe, Co and Ni ions and NaBH4 as reducing agents in oil-in-water microemulsion system. The prepared MNP were used as catalyst in 4-Nitro phenol (4-NP) reduction to 4-Aminophenol (4-AP). It was found that magnetic Co MNP performed superior catalytic performances than Fe and Ni MNP for 4-NP reduction. The catalytic reduction experiments revealed that as the concentration of reducing agent, NaBH4 that was used in the preparation of Co MNP was increased, the complete conversion time for 4-NP to 4-AP was decreased as the sizes ...More

Article 2020 Mühendislik Fakültesi Inorganic Chemistry Communications116 108 Views
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A novel highly sensitive carbon-based HMPD/GC sensor electrode: copper ions analysis in flour and water samples

Ali Osman SOLAK

In this research, (Z)-2-(2-(hydroxyimino)-2-(3-methyl-3-phenylcyclobutyl) ethyl)-3a,7a-dihy-dro-1H-isoindole-1,3(2H)-dione, HMPD molecule has been grafted to the glassy carbon (GC) electrode surface. The HMPD-modified GC electrode has been originally developed and it used for the quantitative determination of Cu(II) in flour and water samples. The modification steps have been performed using cyclic voltammetry (CV). CV, electrochemical impedance spectroscopy and scanning electron microscopy have been employed for the characterization processes. Cu(II) standard solutions changing from 1.0 x 10( ...More

Article 2018 Mühendislik Fakültesi Desalination and Water Treatment112 56 Views
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