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Synthesis, Characterization, and Investigation of Coating Properties of Carboxymethyl Acorn Starch (CMAS)

Nurzat ŞAYKİYEVA | Mirlan MOLDOBAYEV | Kubat KEMELOV | Canıl İSKAKOVA | Mustafa DOLAZ

Kyrgyzstan is a landlocked country in Central Asia, famous for its crystal-clear lakes, majestic Tien Shan Mountains that bisect the territory of Turkistan, and magnificent natural beauty. This study aims to evaluate the fruit (acorns) of the oak trees (Quercus robur L.) grown in Bishkek, the capital city of Kyrgyzstan. For this purpose, carboxymethyl acorn starch (CMAS), which is not synthesized in literature, is first synthesized by isolating acorn starch (AS) from the acorns. The structures of CMASs are characterized by H-1(C-13)-NMR, FT-IR, XRD, and SEM techniques. The viscosities of the s ...More

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The Oxidation Behavior of Potato Starch and Benzyl Alcohol via Peroxide in the Catalysis of Metal Complexes

Mustafa DOLAZ

Two new Schiff bases ligands (HL1 and HL2) and their Co2, Mn2, Fe3, Ru3, Cr3, and VO2 complexes were synthesized and characterized by FT-IR, 1H-NMR, and Mass spect. and analytical methods. A single-crystal X-ray diffraction study determined the molecular structure of HL1. The catalytic effects of metal complexes on benzyl alcohol and potato starch (PS) oxidation were compared in an H-2O-2 medium. The percent conversion of benzyl alcohol to benzaldehyde and benzoic acid was determined by Gas Chromatography. [Co(L-1)(2)], [Mn(L-1)(2)], [Co(L-2)(2)], and [Mn(L-2)(2)] showed the highest catalytic ...More

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Synthesis and Characterization of Hydroxypropyl Acorn Starch (HPAS) From Oak Acorn

Mustafa DOLAZ

The utilization of forest auxiliary products and their conversion into products with higher added value is important for the use of renewable resources. For this purpose, acorns belonging to the Q. coccifera species were collected in November, which is their ripening period, and dried and ground in the laboratory. Then, acorn starch (AS) was isolated from the sieved acorn flour. For 5 g of this isolated AS, hydroxypropyl acorn starch (HPAS) with the highest molar substitution (MS = 0.319) was synthesized by optimizing at 45 degrees C for 5 h with 30 g of propylene oxide and 1.88 g of NaOH. The ...More

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Synthesis and Characterization of Hydroxyethyl Starch from Chips Wastes Under Microwave Irradiation

Mustafa DOLAZ

This article focuses on the synthesis of hydroxyethyl potato starch (HEPS) for liquid hand soap by evaluating waste potato starch (WPS), a byproduct in potato chips production. It is a cheap, biodegradable, non-toxic and renewable natural polymer, available in great quantities on a global level. In a factory producing potato chips, WPS, which remained in the aqueous medium during peeling, slicing, and washing the potatoes, was purified at the desired temperature with H2O2 and NaOH. HEPSs with the molar substitution (MS) in the range from 0.298 to 0.670, were synthesized under microwave irradia ...More

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