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Найденный: 18 Экземпляр 0.002 sn
Факультет / Институт [1]
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Arsenic Removal by Electrocoagulation

Mehmet KOBYA

Because of the toxic impacts on human health, the arsenic (As) limit value in drinking water was decreased from 50 to 10 μg l −1 by the relevant authorities (WHO 1993; US EPA 2001). In this case, the problem of As pollution in natural water resources used for drinking water has grown even more and turned into a global crisis. According to reports in many parts of the world, over about 230 million people appear to be affected by high arsenic concentrations in groundwater. In this case, it turned out that there was a great need for cost-effective and environmentally friendly technologies from dr ...Более

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Carbon Nanotube Supported CdM(S, Se)/CdTe Anode Catalysts for Electrooxidation of Glucose in Alkaline Media

Hilal DEMİR KIVRAK | Nahit AKTAŞ

The sequential sodium borohydride (SBH, NaBH4) reduction method was utilized to prepare the 0.1 CdSe/CNT, 0.1 CdS/CNT, 0.1 (CdS-CNT)/CdTe, and 0.1 (CdSe-CNT)/CdTe catalysts. The XRD, SEM-EDS, TEM, and XPS analyses were used to characterize the catalysts. The electrochemical measurements were examined by cyclic voltammetry (CV), chronoamperometry (CA), and electrochemical impedance spectroscopy (EIS) analyses for glucose electrooxidation. The characterization analyses revealed that the desired structure was formed on the support material. The electrochemical analysis results indicated that the ...Более

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Fabrication of molecularly imprinted cotton fibers for quantification of streptomycin in honey samples

Nahit AKTAŞ

Streptomycin is a type of aminoglycoside used in treatment of several infections and with serious side effects in humans and animals, such as ototoxicity and nephrotoxicity. In the present study, we focused on the preparation of streptomycin-imprinted cotton fiber for rapid, sensitive and selective quantification of streptomycin in honey samples. The imprinted cotton fibers were characterized by attenuated total reflectance-Fourier transform spectroscopy, scanning electron microscopy, and x-ray photoelectron spectroscopy. In addition, the imprinted cotton fibers showed high adsorption capacity ...Более

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Synthesis, Characterization, and Investigation of Coating Properties of Carboxymethyl Acorn Starch (CMAS)

Nurzat ŞAYKİYEVA | Mirlan MOLDOBAYEV | Kubat KEMELOV | Canıl İSKAKOVA | Mustafa DOLAZ

Kyrgyzstan is a landlocked country in Central Asia, famous for its crystal-clear lakes, majestic Tien Shan Mountains that bisect the territory of Turkistan, and magnificent natural beauty. This study aims to evaluate the fruit (acorns) of the oak trees (Quercus robur L.) grown in Bishkek, the capital city of Kyrgyzstan. For this purpose, carboxymethyl acorn starch (CMAS), which is not synthesized in literature, is first synthesized by isolating acorn starch (AS) from the acorns. The structures of CMASs are characterized by H-1(C-13)-NMR, FT-IR, XRD, and SEM techniques. The viscosities of the s ...Более

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p(thyme oil) and p(clove oil) organo-particles with biocompatible, anticancer, antioxidant, and antibacterial properties against Capan-1 and L-929 cells

Nahit AKTAŞ

The synthesis of p(ClO) and p(TO) organo-particles from clove oil and thyme oil is the first in the literature. The particles were tested against the L-929 cell line for cell viability/cytotoxicity. The anticancer activity was studied against the Capan-1 pancreatic cancer cell line. p(ClO) and p(TO) organo-particles were featured by thermogravimetry (TGA), Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), particle size (DLS), and particle charge (zeta potential, Zeta) analyses. Antioxidant, biocompatible, antimicrobial, and in vitro cytotoxicity specialties w ...Более

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Synthesis of poly(Oak bark) particles from oak bark extract and its utilization as a drug carrier material

Nahit AKTAŞ

As oak bark extract includes pharmaceutically meaningful precious biochemicals such as vanillic acid, quercetin, catechin, caffeic acid, gallic acid, ferulic acid, syringic acid, chlorogenic acid, q-coumaric and protocatechuic acid, the present study focuses on synthesizing polymeric particles from that extract while keeping their targeted natural bioactivity. In this study, due to the bioavailability of oak bark extracts, poly(Oak bark)water extract (p(OB)w), poly(Oak bark)ethanol extract (p(OB)e) and poly(Oak bark)water-ethanol extract (p(OB)we) particles were synthesized using redox polymer ...Более

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Fabrication of an Electrochemical E. coli Biosensor in Biowells Using Bimetallic Nanoparticle-Labelled Antibodies

Ali Osman SOLAK

An electrochemical biosensor was developed for the determination of Escherichia coli (E. coli) in water. For this purpose, silver-gold core-shell (Ag@Au) bioconjugates and anti-E. coli modified PS-microwells were designed in a sandwich-type format in order to obtain higher sensitivity and selectivity. Ag@Au bimetallic nanoparticles were synthesized by co-reduction method. The core-shell formation was analyzed by using UV-Vis spectroscopy and transmission electron microscopy. Biotin labeled anti-E. coli antibodies were coupled with Ag@Au nanoparticles to form bioconjugates. The electrochemical ...Более

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Evaluation of Some Redox Mediators in the Design of Reagentless Amperometric Glucose Biosensor

Ali Osman SOLAK

The influence of redox mediators (tetrathiafulvalene (TTF), tetrathiafulvalene-tetracyanoquinodimethane complex (TTF-TCNQ), phenazine methosulfate (PMS), 5,6-diamino-1,10-phenonthroline (5,6-DAP), potassium ferrocyanide (K4[Fe(CN)6]), methylene blue (MB) and toluidine blue (TB)) on the response of amperometric glucose biosensor was investigated in this research. Graphite rod electrode (GRE) modified by adsorbed mediator and glucose oxidase (GOx) cross-linked with glutaraldehyde was served as working electrode. The highest amperometric signals were observed by using TTF and TTF-TCNQ as mediator ...Более

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Synthesis, characterization, and application of silver nanoparticle-thiophenol nanocomposite film on the glassy carbon surface

Ali Osman SOLAK

In this study, 4-thiophenol modified glassy carbon electrode was prepared by the reduction of 4-diazothiophenol tetrafluoroborate salt. Silver nanoparticles were attached to the thiophenol modified surface to prepare a thiophenol-silver nanoparticle composite film. 4-Aminothiopenol molecules were deposited by self-assembling technique to form multi-layered nanofilms of TP/SNP/PhNH2 on glassy carbon substrate. These surfaces were characterized by cyclic voltammetry, electrochemical impedance spectroscopy, X-ray photoelectron spectroscopy, reflectance-absorption infrared spectroscopy, and ellips ...Более

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Biofuel Cell Based on Anode and Cathode Modified by Glucose Oxidase

Ali Osman SOLAK

A single compartment biofuel cell (BFC) based on an anode and a cathode powered by the same fuel glucose is reported. Glucose oxidase (GOx) from Aspergillus niger was applied as a glucose consuming biocatalyst for both anode and cathode of the BFC. The 5-amino-1,10-phenanthroline modified graphite rod electrode (GRE) with cross-linked GOx was used as the bioanode, and the GRE with co-immobilised horseradish peroxidase and GOx was exploited as the biocathode of the BFC. The open-circuit voltage of the designed BFC exceeded 450 mV and a maximal power density of 3.5 µW/cm2 was registered at a cel ...Более

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Detection of Escherichia coli O157:H7 using immunomagnetic separation and mPCR in Turkish foods of animal origin

Zafer GÖNÜLALAN

The present study was conducted to investigate the presence of Escherichia coli O157:H7 in food samples of animal origin and to detect its virulence genes by immunomagnetic separation technique and multiplex PCR (mPCR). A total of 500 samples (consisting of diced meat, minced meat, burger, raw cow's milk and raw cow's milk cheese) were analysed. Escherichia coli O157:H7 was detected in 5 (1%) of 500 analysed samples including two diced meat, one minced meat and two raw-milk cheese. None of the burger samples tested contained E. coli O157:H7. Three isolates obtained from minced and diced meat w ...Более

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Modification of glassy carbon electrode by the electrochemical oxidation of 3-aminophenylcalix[4]pyrrole in nonaqueous media

Ali Osman SOLAK

3-Aminophenylcalix[4]pyrrole (3APCP) was grafted to a glassy carbon (GC) surface during the electrochemical oxidation process in 0.1 M tetrabutylammoniumtetra-fluoroborate (TBATFB) containing acetonitrile solution. The presence of a surface film was confirmed electrochemically by comparing voltammograms of dopamine and ferricyanide redox probes at the bare and modified electrodes. Reflection-absorption infrared spectroscopy (RAIRS), XPS, atomic force microscopy (AFM), ellipsometry and the contact angle measurements were also employed to characterize 3APCP film on GC electrode. RAIRS analysis r ...Более

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