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Издатель : Springer ✕Источник : Theoretical Foundati ... ✕

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Concentration Distribution of Molecules and Other Species in the Model System Fe-NaCl-Na2S-H2SO4-H2O at Various Temperatures of the Electrocoagulation Process

Zarlık MAYMEKOV | Canarbek İZAKOV | Nurzat ŞAYKİYEVA | Mustafa DOLAZ | Mehmet KOBYA

Under practical conditions, one of the possible solutions to the problem of treatment of hydrogen-sulfide-containing industrial wastewater is the electrochemical oxidation of sulfides. In this work, the model system Fe-NaCl-Na2S-H2SO4-H2O is considered, an experimental setup is constructed, and the electrocoagulation process is studied in a wide (288-308 K) range of temperatures of an aqueous solution of hydrogen sulfide. The optimal ratios between the initial components in the system are determined. The experimental and calculated pH of the solution are found. The system is thermodynamically ...Более

Статья 2023 Mühendislik Fakültesi Theoretical Foundations of Chemical Engineering57 ( 2 ) 74 Просмотры

Possibilities for Prediction And Evaluation of the Carbon Footprint in Furnace Fuel Oil Combustion in Medium- and Low-Power Boilers

Mirlan MOLDOBAYEV | Zarlık MAYMEKOV

To predict and evaluate the carbon footprint in the gas phase, furnace fuel oil oxidation in excess air (alpha factor 1.3) was studied over a wide temperature (T 298–3000 K, P 0.1 MPa). Equilibrium thermodynamic parameters (entropy, enthalpy, and internal energy) and the concentration distributions of C-, S-, N-, O-, and H-containing components and active particles in the gas phase were determined. Based on the total concentration distribution of C-, S-, N-, O-, and H-containing components and active particles in the gas phase, the weight content of carbon was calculated. Taking into account t ...Более

Статья 2023 Mühendislik Fakültesi Theoretical Foundations of Chemical Engineering57 ( 5 ) 5 Просмотры

Electrochemical Sulfur Removal at Controlled and Uncontrolled pHs with an Iron Anode

Nurzat ŞAYKİYEVA | Mustafa DOLAZ | Zarlık MAYMEKOV | Mehmet KOBYA

In this study, sulfide removal was carried out in the Electrocoagulation process under controlled and uncontrolled pH conditions. Under optimum conditions, electrocoagulation took place in less than 40 minutes at uncontrolled pH and less than 30 minutes at controlled pH to reduce the sulfite concentration of the effluent below 0.5 mg/L. The reaction rate constant and iron-sulfide molar ratio for sulfide removal were 14.09 x 10(-2) min(-1) and 0.97 mol/mol, respectively; under uncontrolled pH conditions, they were 22.88 x 10(-2) and 0.97 mol/mol at controlled pH. The mg sulfide removed per g Fe ...Более

Статья 2023 Mühendislik Fakültesi Theoretical Foundations of Chemical Engineering57 ( 6 ) 6 Просмотры

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