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Erişime Açık

Ultrasound-assisted photocatalytic decomposition of rifadin with biochar and CNT-based NiCr layered double hydroxides

Mehmet KOBYA

Modification of layered double hydroxides (LDHs) is known to be beneficial for boosting the consistent formation of reactive oxygen species (ROSs) and enhancing the photocatalytic process. Herein, a facile synthesis method for preparing carbon nanotube (CNT) and biochar (BC)-based NiCr LDH (NC) nanocomposites as a sonophotocatalyst for the efficient degradation of rifadin (RA) was provided. The formation of thin nanosheet structures of NC along with porous and nanotube structures of BC and CNT was well approved by scanning electron microscope (SEM) and high-resolution transmission electron mic ...Daha fazlası

Erişime Açık

Carbonaceous CoCr LDH nanocomposite as a light-responsive sonocatalyst for treatment of a plasticizer-containing water

Mehmet KOBYA

The carbonous-based nanocomposites of CoCr layered double hydroxide (LDH) with graphene oxide (GO) and reduced graphene oxide (rGO) were prepared. The successful synthesis of the CoCr LDH in hydrotalcite crystalline structure was deduced from the pattern obtained from X-ray diffraction, and the chemical composition of its surface was checked by X-ray photoelectron spectroscopy. The prosperous decorating of LDH on the sheets of rGO and GO was authenticated by the energy dispersive X-ray spectroscopy analysis and micrographs of scanning electron and transmission electron microscopy. The photo-as ...Daha fazlası

Erişime Açık

Zinc-chromium layered double hydroxides anchored on carbon nanotube and biochar for ultrasound-assisted photocatalysis of rifampicin

Mehmet KOBYA

In this study, ZnCr layered double hydroxide (LDH), ZnCr LDH/carbon nanotube (CNT), and ZnCr LDH/Biochar (BC) were synthesized and characterized by various analyses. The successful synthesis and the great crystallinity of the samples were consented by XRD analysis. SEM and TEM were applied to study the morphology of the synthesized samples. The simultaneous presence of C, Zn, and Cr elements was well confirmed by EDX and dot mapping analyses demonstrating the successful preparation of nanocomposites. According to the BET analysis, ZnCr LDH nanocomposites with BC and CNT had more specific surfa ...Daha fazlası

Erişime Açık

Graphene-based ZnCr layered double hydroxide nanocomposites as bactericidal agents with high sonophotocatalytic performances for degradation of rifampicin

Mehmet KOBYA

Herein, ZnCr layered double hydroxide (ZnCr LDH), and its nanocomposites with GO and rGO were synthesized using the co-precipitation method. The samples were characterized using XRD, FT-IR, SEM, TEM, BET, and XPS techniques. The sonophotocatalytic activity of the ZnCr LDH, ZnCr LDH/GO, and ZnCr LDH/rGO was investigated via the degradation of rifampicin (RIF) in the ultrasonic bath under visible light irradiation. The synergy index of more than 1 determined for ZnCr LDH/rGO indicated the positive interaction of sonocatalysis and photocatalysis resulted by hybridizing the LDH nanosheets with rGO ...Daha fazlası

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